Zein adsorbents with micro/nanofibrous membrane structure for removal of oils, organic dyes, and heavy metal ions in aqueous solution

Developing multi-functional media for effectively removing different contaminants coexisted in wastewater system is highly desired. Herein, zein, a natural protein possessing abundant functional groups in molecule, is chosen to be fabricated into micro/nanofibrous membranes as adsorbents and separation media. Zein fibers with novel groove ribbon structures, which possess better structural characteristics, are designed for obtaining good adsorption performance. The adsorption performances of zein fiber membranes are evaluated. The results show that zein fiber membranes have the adsorption capacities up to 94 g/g for motor oil, 168 mg/g for Congo red, and 189 mg/g for Pb2+ ion for 1000 mg/L initial solution concentration, showing considerable competitiveness as compared with the reported adsorbents. The zein membrane with groove ribbon fiber morphology exhibits optimal adsorption capability and can be attractive multi-functional separation media.

Automated summary

The research focuses on developing multi-functional media using zein, a natural protein, to effectively remove different contaminants in wastewater system. Zein fiber membranes show high adsorption capacities for motor oil, Congo red, and Pb2+ ion, making them competitive compared to reported adsorbents. The zein membrane with groove ribbon fiber morphology demonstrates optimal adsorption capability and can serve as attractive multi-functional separation media.