Enhanced electro-oxidation performance of FeCoLDH to organic pollutants using hydrophilic structure

Iron-cobalt layered double hydroxides (FeCoLDH) showed superior oxygen evolution reaction (OER) performance, but the sluggish water adsorption and dissociation dynamics restrict its capacity to degrade organic pollutants by electro-oxidation. Herein, enhanced electro-oxidation performance of FeCoLDH with hydrophilic structure was designed and exhibited efficient removal efficiency of tetracycline. Theoretical calculation and characterization results consistently elucidated that the electronic structure of FeCoLDH is optimized by doping phosphorus and depositing copper nanodots (NDs). In addition, the obtained Cu NDs/P-FeCoLDH shows higher degradation ability of tetracycline in all-pH conditions than pristine FeCoLDH. That's because it owns smaller barrier with 0.6 eV to generate hydroxyl radicals (center dot OH) than pristine FeCoLDH. Furthermore, it can effectively degrade organic pollutants in seawater, river water and pharmaceutical wastewater samples. This work provides novel and rational electrode materials for electro-oxidation system with practical application potential, which could offer new insights into the fundamental understanding of electrochemistry.

Automated summary

The article discusses the enhanced electro-oxidation performance of iron-cobalt layered double hydroxides (FeCoLDH) by doping phosphorus and depositing copper nanodots (NDs). The modified FeCoLDH showed higher degradation ability of tetracycline in various pH conditions and effectively degraded organic pollutants in different water samples. This work provides new electrode materials for electro-oxidation systems with practical application potential and contributes to the fundamental understanding of electrochemistry.