期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 257, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2022.109971
关键词
Trifluoromethyl; Alkynes; Epoxides; Felkin-Anh model; Hydride migration
The utilization of 3,3,3-trifluoroprop-1-yne in the presence of BF3·OEt2 was demonstrated to achieve regio- and stereoselective ring opening of various epoxides, leading to the synthesis of CF3-containing homopropargylic alcohols in high yields.
Utilization of 3,3,3-trifluoroprop-1-yne for the regio-as well as stereoselective ring opening of a variety of epoxides by the assistance of BF3 center dot & nbsp;OEt2 was demonstrated which successfully furnished the corresponding CF3- containing homopropargylic alcohols in good to excellent yields.
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