Study on single step solid state synthesis of WC@C nanocomposite and electrochemical stability of synthesized WC@C & Pt/WC@C for alcohol oxidation (methanol/ethanol)

WC@C nano composite was prepared by a single step solid-state reaction through in situ reduction and carburization of WO3 in the presence of Mg and activated charcoal. The XRD results and thermodynamics analysis showed that the optimization of reaction temperature facilitates the reduction as well as carburization of tungsten oxide(s) at different reaction temperature. Thermogravimetric analysis of the product was done to assess the thermal stability in air. The Raman spectroscopy was used to find out the nature (amorphous/graphitic) of carbon in the obtained phase. The N-2 adsorptionedesorption measurement showed a narrow pore size distribution from 3 to 4 nm with BET surface area of up to 522.5 m(2)/g. TEM/HRTEM images confirmed formation of the WC nano particles with spherical morphology. Electrochemical stability of pure and platinized carbide sample (Pt/WC) has been investigated using cyclic voltammetry in acidic media for alcohol (methanol and ethanol) oxidation. (C) 2016 Published by Elsevier B.V.