4.1 Article

Surface adsorption structure determination using backscattering photoelectron diffraction

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DOI: 10.1016/j.elspec.2022.147170

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Surface structure; Photoelectron diffraction; Atomic adsorption; Molecular adsorption; Electron scattering; XPS

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The paper provides a historical introduction and explains the distinction between two modes of photoelectron diffraction and two modes of data collection. It reviews the energy-scan backscattering photoelectron diffraction technique and presents examples of its application. The paper also discusses future prospects for the technique.
Following a brief historical introduction, the distinction between two modes of photoelectron diffraction, highenergy forward scattering and low energy backscattering, and two modes of data collection, angle-scan and energy-scan, is explained. This is followed by a review of energy-scan backscattering photoelectron diffraction (PhD). Examples are presented of atomic adsorption and molecular adsorption on metal surfaces and molecular adsorption on oxide surfaces. The paper ends with a brief survey of future prospects for the application of the PhD technique.

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