期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 911, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2022.116203
关键词
Lithium-ion battery; Anode; ZIF-67; Cobalt sulfide
资金
- Project of Ningxia Key RD Plan [2021BEE03006]
In this study, 3D cobalt sulfide/carbon polyhedral hybrids were prepared using ZIF-67 as a template. The results showed that CoS2 played a significant role in the lithium ion battery performance of CoSx/CP. The optimized CoSx/CP exhibited various electrochemical reactions and the lowest charge transfer resistance.
In this work, the 3D cobalt sulfide/carbon polyhedral (CoSx/CP) hybrids (x = 1, 2) have been fancily prepared by employing the ZIF-67 as template. The as-prepared CoSx/CP inherit the structure of ZIF-67, realizing the polyhedral structure where the CoSx nanoparticles are well embedded. The battery performance measurements demonstrate that the CoS2 has played a significant role contributing to the lithium ions batteries (LIBs) performance of CoSx/CP. As a result, the capacity of the optimized CoSx/CP is 562 mAh g(-1) after 300 cycles at 0.5 A g(-1). When cycled at 10 A g(-1), it delivers a reversible specific capacity of 131 mAh g(-1). The electrochemical analysis points out that the optimized CoSx/CP possesses diverse electrochemical reactions and the lowest charge transfer resistance. Moreover, the insertion mechanism and structural evolution process of CoSx/CP are examined by the in-situ XRD. Beyond that, the unique nanoarchitecture of CoSx/CP guarantees the high specific surface area which enables the large electrode-electrolyte contract area, fast ions diffusion/electron transfer and robust structural stability. Meanwhile, the carbon skeleton is deductive to confine the huge volume expansion of CoSx as well.
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