Construction of Z-scheme heterojunction by coupling Bi2Sn2O7 and BiOBr with abundant oxygen vacancies: Enhanced photodegradation performance and mechanism insight

Promoting charge migration and enhancing redox ability of photogenerated carriers are important for the development of highly efficient semiconductor-based photocatalyst. Here, BiOBr/Bi2Sn2O7 heterojunction with oxygen vacancies (OVs) was constructed by homogeneously depositing Bi2Sn2O7 nanoparticles on the Vo-BiOBr surface. The experimental results manifested that Vo-BiOBr/Bi2Sn2O7 displayed better performance for rhodamine B, ciprofloxacin, and tetracycline degradation than counterparts without OVs. The characterization results proved OVs played the essential role for enhanced performance via improving the separation efficiency of charge carriers, increasing the visible light harvest, and lowering conduction band position. Moreover, mechanism study revealed that an inner electric field was built at the interface, leading to a Z-scheme path of photogenerated electron. This study provided an efficient strat-egy for designing highly efficient photocatalyst for solving environmental pollution. (c) 2022 Elsevier Inc. All rights reserved.

Automated summary

The BiOBr/Bi2Sn2O7 heterojunction with oxygen vacancies (OVs) was constructed by depositing Bi2Sn2O7 nanoparticles on the Vo-BiOBr surface. The results showed that the heterojunction with OVs exhibited better performance in degrading pollutants. The OVs enhanced the performance by improving charge carrier separation efficiency, increasing visible light absorption, and decreasing the conduction band position.