Ni3Se4@CoSe2 hetero-nanocrystals encapsulated into CNT-porous carbon interpenetrating frameworks for high-performance sodium ion battery

Core-shell structured Ni-ZIF-67@ZIF-8 derived bimetal selenides encapsulating into a 3D interpenetrating dual-carbon framework (Ni3Se4@CoSe2@C/CNTs) have been designed and prepared via carbonization and subsequent selenization processes. In this hierarchical structure, Ni3Se4@CoSe2 nanocrystals were uniformly dispersed into the 3D carbon framework structure/carbon nanotubes networks, which greatly enhanced the electronic conductivity and further enabled ultrafast Na-ion diffusion kinetics. When used as anode materials of sodium ion battery (SIB), The Ni3Se4@CoSe2@C/CNTs electrode delivered the excellent rate capability of 206 mA h g-1 at 3 A g-1 and marvelous cyclic stability with capacity retention of 243 mA h g-1 after 600 cycles at 1 A g-1. This research provides a new way to prepare bimetallic selenide derived from MOF precursor with amazing heterostructure as the advanced anode materials for SIBs. (c) 2021 Elsevier Inc. All rights reserved.

Automated summary

A new type of Ni3Se4@CoSe2@C/CNTs electrode material with core-shell structured selenides encapsulated into a 3D interpenetrating dual-carbon framework has been designed and prepared. This material exhibits excellent rate capability and cycling stability, providing a new approach for the anode materials of sodium ion batteries.