期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 899, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.163267
关键词
Supercapacitor; CoMoO4; Nanosheet; Nanoarrays; Composite materials
资金
- National Natural Science Foundation of China [51702059]
- Natural Science Foundation of Guangxi Province [2020GXNSFAA297268, 2017GXNSFBA198131]
- Innovation-Driven Development Foundation of Guangxi Province [AA17204063]
- Science and Technology Plan Project of Chongzuo [FA2019001]
The Ni-Co-Mo oxides composite materials exhibit good electrochemical performance with a unique nanostructure, achieving a high specific capacitance of 1837.7 F g(-1) at 1 A g(-1) and maintaining capacitance retention of 81.2% at 5 A g(-1). The fabricated hybrid capacitor also achieves high specific energy of 41.1 W h kg(-1), indicating its potential for application in supercapacitors.
Multi-metal oxide materials have gained increasing attention due to their superior electrochemical performance for supercapacitors. In this work, Ni-Co-Mo oxides composite materials (NiCoMo/NF) are synthesized and anchored on Ni foam in the form of vertically aligned nanosheet arrays using a two-step hydrothermal method. It has confirmed that good electrochemical performance stems from a synergic interaction effect between the hybrid Ni-Co-Mo composite materials and the co-existence of Ni-Co and Co-Mo oxide, which can be attributed to a unique nanostructure in the hybrid Ni-Co-Mo composite materials and Ni-Co/Co-Mo oxide intersections with each other. The NiCoMo/NF binder-free electrode shows an enhanced specific capacitance of 1837.7 F g(-1) (3.31 F cm(-2)) at a current density of 1 A g(-1) and maintains capacitance retention of 81.2% after 6000 cycles at 5 A g(-1). Meanwhile, the fabricated hybrid capacitor achieves high specific energy of 41.1 W h kg(-1). The results indicate that NiCoMo/NF has the potential for application in supercapacitors. Moreover, our work provides a practical approach for fabrication of multi-metal oxide materials and hold promise for high-power energy storage devices. (C) 2021 Elsevier B.V. All rights reserved.
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