Construction of carbon covered Mg2NiH4 nanocrystalline for hydrogen storage

Decreasing the desorption temperature and formation enthalpy are two key challenges for the practical application of magnesium-based hydrogen storage materials. In this paper, different Mg2Ni samples were successfully synthesized, and the corresponding hydrogen storage kinetic and thermodynamic behaviors were investigated. The carbon-covered nanocrystalline Mg2Ni started to take up hydrogen at room temperature and released hydrogen at 180 degrees C. Meanwhile, the hydrogenated sample fully desorbed hydrogen at 250 degrees C within 10 min, and absorbed 2.1 wt% hydrogen in 1 h at 125 degrees C. The absorption and desorption activation energy of carbon-covered nanocrystalline Mg2Ni was calculated to be 20.8 +/- 1.2 kJ/mol and 34.1 +/- 2.4 kJ/mol, which were 74% and 78% lower than that of MgH2, respectively. The dehydrogenation enthalpy of the carbon-covered nanocrystalline Mg2NiH4 sample was also reduced from 89.9 +/- 4.0 kJ/mol of MgH2 to 67.0 +/- 0.5 kJ/mol. In addition, the cycling kinetics was maintained after ten cycles. Further analysis revealed that the remarkably improved hydrogen storage property of Mg2NiH4 originated from the combining effect of the alloying, carbon covering, and nanocrystalline strategy. (C) 2022 Elsevier B.V. All rights reserved.

Automated summary

In this study, various Mg2Ni samples were successfully synthesized and their hydrogen storage properties were investigated. The results showed that the carbon-covered nanocrystalline Mg2Ni exhibited hydrogen uptake and release at relatively low temperatures, with lower activation energy and dehydrogenation enthalpy compared to MgH2. Furthermore, the sample maintained good hydrogen storage performance after multiple cycles.