期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 47, 期 36, 页码 16272-16282出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2022.03.130
关键词
SrFeO 3; Electrode material; Electrochemical activity; Fe-O bond; Symmetrical solid oxide fuel cell
资金
- Science and Technology Foundation of Zhongshan [2019B2028]
- University Innovation Foundation of Guangdong Province [2018KTSCX297]
- Guangdong Basic and Applied Basic Research Foundation [2020A1515010797]
- Major Project of So-cial Public Science and Technology Research of Zhongshan City [2019B2001]
- Science and Technology Foundation of Guangdong Province [2021A0101180005]
- Social Public Research Project of Zhongshan City [2019B2016]
SrFe0.9-xW0.1TixO3-$ perovskite oxides were synthesized by combustion process. The effects of dopant W and Ti on material properties and structure were investigated experimentally and computationally. It was found that optimizing the Ti content could improve the conductivity and stability of the materials.
SrFe0.9-xW0.1TixO3-$ (SFWT, x = 0.1 and 0.2) perovskite oxides are synthesized by combustion process. The experimental and computational analyses are conducted to reveal the effect of dopant W and Ti on the material properties and structure. The crystal structure transform from tetragonal (I4/m) to cubic(pm3m) when temperature is higher than 700 degrees C. Substitution of Fe with Ti can enhance the lattice structure. However, the Ti incorporation causes the increase in thermal expansion coefficient above 700 degrees C. The XPS and TG analyses show that the Ti incorporation also decreases oxygen activity. Thus, it is important to optimize the Ti content to design the SFWT materials to gain fast kinetics and high stability. The total conductivity (48 S cm-1), polarization resistances of symmetric single cell (0.28 U cm2), and durability (150 h, at 750 degrees C) reveal that the SrFe0.8W0.1Ti0.1O3-$ is a promising electrode materials for symmetric fuel cell. The first-principles calculation suggests that the Fe-O bond in SFWT dominates electric conductivity and can be suitably tailored by the dopant Ti and W. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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