Characterization of raw and alkali treated cellulosic Grewia Flavescens natural fiber

The physicochemical, mechanical, thermal as well as morphological characteristics of alkali treated cellulosic Grewia Flavescens are reported in this paper. Using standard test methods, the chemical constituents of Grewia Flavescens fiber (GFF) are evaluated. Fiber treated in 5% (w/v) NaOH for 45 min soaking time is regarded as optimally surface-modified fiber. After optimal alkalization, there is an enhancement of cellulose content from 58.46% to 68.31%. Mechanical properties of GFF are determined by single fiber tensile test and improved tensile strength is achieved after alkalization. Weibull statistical analysis is performed for diameter and mechanical parameters of raw as well as treated GFF. FTIR spectroscopy reveals the removal of amorphous material from the fiber post-treatment and XRD analysis confirms improvement in crystallinity index from 16.01% to 26.72% and crystal size from 62.90 nm to 68.43 nm after alkalization. Thermal stability and thermal degradation temperature are found to be improved after alkali treatment. Morphological analysis of raw and alkali treated cellulosic GFF shows enhanced rough surface of fiber after alkalization because of elimination of impurities and foreign particles from the fiber surface. Presently studied GFF seems to be a good substitute to the harmful man-made fibers for making of bio composites.

Automated summary

This paper reports the physicochemical, mechanical, thermal, and morphological characteristics of alkali treated cellulosic Grewia Flavescens. The study found that alkali treatment improved the cellulose content, tensile strength, crystallinity index, thermal stability, and surface roughness of the fiber. The results suggest that Grewia Flavescens fiber could be a good substitute for harmful man-made fibers in the production of bio composites.