4.7 Review

A recent advancement on preparation, characterization and application of nanolignin

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Sustainable production of lignin micro-/nano-particles (LMNPs) from biomass: Influence of the type of biomass on their self-assembly capability and physicochemical properties

Zhicheng Jiang et al.

Summary: This study carefully prepared lignin micro/nano-particles (LMNPs) from various types of biomass, yielding uniform and spherical LMNPs with eco-friendly features and biological compatibility. The presence of specific linkages in the ligno-oligomers from different biomass affected the self-assembly capability of LMNPs, with stable and spherical LMNPs obtained from corncob residue and pine wood showing promising potential for various applications.

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Recovery of nanosized silica and lignin from sugarcane bagasse waste and their engineering in fabrication of composite membrane for water purification

Baljinder Singh Kauldhar et al.

Summary: A catalytic process utilizing acid catalyst and a combination of peroxide and base was developed to convert sugarcane bagasse into functional nanomaterials. The synthesized silica and lignin nanomaterials were used to fabricate a functional membrane for purification of solute particles and gases, showing promising results for filtration of contaminated water and air purification.

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Lignin-Based Polyethylene Films with Enhanced Thermal, Opacity and Biodegradability Properties for Agricultural Mulch Applications

Lucio R. Chiappero et al.

Summary: Lignins are investigated as promising alternative raw materials for biocomposites, showing positive effects on the performance of LLDPE films, especially when modified by esterification. Lignin-based blends exhibit improved weight loss performance after soil buried test.

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Lignin-based nanoparticles for recovery and separation of phosphate and reused as renewable magnetic fertilizers

Tao Li et al.

Summary: Magnetic lignin-based nanoparticles were developed for phosphorus adsorption and slow-release fertilizer, showing potential as efficiently separated and renewable nanomaterial for removal of low concentration phosphate in wastewater treatment and sustainable agriculture. The nanoparticles released increasing amounts of iron and phosphorus in soil, and can be separated with high recovery ratio and regenerated for phosphate recovery again.

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Lignin for Bioeconomy: The Present and Future Role of Technical Lignin

Adam Ekielski et al.

Summary: This paper evaluates the current status of lignin valorization in commercial products, noting that technical lignin-based commercial products leverage the coarse properties of technical lignin. Challenges are encountered in lignin-based nanotechnology and lignin-centric investigations, highlighting the gap between lab-scale applications and lignin-based commercial products.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2021)

Review Biochemistry & Molecular Biology

Characterization of Lignin Compounds at the Molecular Level: Mass Spectrometry Analysis and Raw Data Processing

Ruochun Zhang et al.

Summary: Lignin, the second largest natural biopolymer, has the potential to replace conventional fossil fuels and recovery of valuable chemicals. Analyzing lignin using mass spectrometry can assess the content of valuable chemicals and contribute to its utilization in chemical synthesis, materials, energy, and geochemistry.

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Preparation and Characterization of Size-Controlled Lignin Nanoparticles with Deep Eutectic Solvents by Nanoprecipitation

Tong Luo et al.

Summary: The study developed a simple and sustainable method to synthesize uniform lignin nanoparticles using deep eutectic solvents, which showed high yield, excellent dispersibility, and long-term stability. This environmentally friendly approach advances the field of lignin-based nanotechnology.

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Production and Properties of Lignin Nanoparticles from Ethanol Organosolv Liquors-Influence of Origin and Pretreatment Conditions

Johannes Adamcyk et al.

Summary: Despite major efforts in recent years, lignin as an abundant biopolymer is still underutilized in material applications. Production of lignin nanoparticles with improved properties through a high specific surface area enables easier applicability and higher value applications. This work provides detailed insight into the precipitation process of lignin nanoparticles, enabling better understanding and optimization with respect to different raw materials and pretreatment severities.

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Summary: Lignin, as one of the largest natural resources in the world, has diverse applications; a better understanding of its chemical structure and valorization methods is crucial. The main challenge lies in the fractionation of lignin to obtain more homogeneous and less complex fractions.

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Self-Assembly Preparation of Nano-Lignin/Cationic Polyacrylamide Complexes

Guoyu Tian et al.

Summary: This study describes the preparation of nano-lignin particles from calcium lignosulfonate (CL) via self-assembly, with an average particle size of approximately 100 nm. The obtained nano-lignin exhibited enhanced fluorescence intensity compared to the original lignin, suggesting potential applications for this nano-particle product.

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Elodie Melro et al.

Summary: Lignin, a complex organic polymer in plant cell walls, plays important biological functions and is undervalued despite being co-produced in large amounts. Through the development of better utilization methods and technologies, lignin can become a key resource for producing green fuels and high-value materials.

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Poly(lactic acid)/lignin films with enhanced toughness and anti-oxidation performance for active food packaging

Weijun Yang et al.

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Assessing the potential of lignin nanoparticles as drug carrier: Synthesis, cytotoxicity and genotoxicity studies

Lubna Siddiqui et al.

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Antimicrobial Tendency of Bagasse Lignin Extracts by Raman Peak Intensity

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Adarsh Kumar et al.

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Fabrication of a versatile lignin-based nano-trap for heavy metal ion capture and bacterial inhibition

Duo Xiao et al.

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Chitosan/nano-lignin based composite as a new sorbent for enhanced removal of dye pollution from aqueous solutions

Saima Sohni et al.

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Biodegradable UV-Blocking Films through Core-Shell Lignin-Melanin Nanoparticles in Poly(butylene adipate-co-terephthalate)

Qianqiu Xing et al.

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A concise review of current lignin production, applications, products and their environmental impact

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Layer by layer supported laccase on lignin nanoparticles catalyzes the selective oxidation of alcohols to aldehydes

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Xiu Wang et al.

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