High-performance multifunctional polyvinyl alcohol/starch based active packaging films compatibilized with bioinspired polydopamine nanoparticles

Bioinspired polydopamine (PDA) nanoparticles were synthesized and explored as functional compatibilizers in polyvinyl alcohol/starch (PVA/ST) matrix to develop high-performance multifunctional packaging film. The effect of the addition of PDA on the microstructural, mechanical, thermal, water vapor barrier, ultraviolet (UV)/high-energy blue light (HEBL) blocking, thermal insulating and antioxidant properties of PVA/ST composite films was fully investigated. Results demonstrated that the added PDA nanoparticles were evenly dispersed in the PVA/ST matrix, providing compact and dense nanocomposite films due to their compatibilization effect. Compared with virgin PVA/ST film, the resulting PVA/ST/PDA nanocomposite films exhibited greatly improved tensile strength, toughness, thermal stability, and water vapor barrier ability. Furthermore, the presence of PDA endowed PVA/ST composite film with excellent UV/HEBL blocking, thermal insulating as well as antioxidant functions. Thus, such high-performance multifunctional nanocomposite films hold the potential of protecting food quality against photothermal oxidative deterioration and extend food shelf life.

Automated summary

The addition of bioinspired polydopamine (PDA) nanoparticles to polyvinyl alcohol/starch (PVA/ST) composite films improves their mechanical properties, thermal stability, water vapor barrier ability, UV/high-energy blue light (HEBL) blocking, thermal insulating, and antioxidant functions. These multifunctional nanocomposite films have the potential to protect food quality and extend shelf life.