期刊
INORGANICA CHIMICA ACTA
卷 532, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2021.120737
关键词
Iridium; Cyclometalated; Tridentate ligand; Triazole; Luminescence; Crystal structure
Nine new iridium(III) complexes with two tridentate ligands were synthesized and two complexes were structurally characterized by X-ray diffraction. These complexes exhibit phosphorescence in the green region of the spectrum, with long lifetimes and relatively high quantum yields. There is some variation in performance depending on the substitution pattern, but complexes with 4-methoxy-substituted ligands show better emission.
Nine new iridium(III) complexes featuring two tridentate ligands have been synthesised of the form Ir((NCN)-C-boolean AND-N-boolean AND) ((-NNN-)-N-boolean AND-N-boolean AND), where (NCN)-C-boolean AND-N-boolean AND represents a cyclometallating ligand based on 1,3-di(2-pyridyl)benzene and (-NNN-)-N-boolean AND-N-boolean AND is a doubly deprotonated bis(1,2,4-triazolyl)pyridine. Three examples of each ligand have been used, with different substituents in the central aryl ring of the former and para-substituted aryl groups in the 5-positions of the triazole rings of the latter. Two of the complexes have been structurally characterised in the solid-state by X-ray diffraction, confirming the mutually orthogonal arrangement of the two ligands. Unlike related triscyclometallated complexes of the type Ir((NCN)-C-boolean AND-N-boolean AND)((CNC)-N-boolean AND-C-boolean AND), which are unstable with respect to photoactivated cleavage of the trans-disposed Ir-C bonds, the new complexes show no evidence of instability. They are phosphorescent in the green region of the spectrum with lifetimes around 200 ns and quantum yields up to 3%, apparently limited by non-radiative decay processes in particular. Although there is some variation in performance with substitution pattern, the only discernible trend is that complexes of the 4-methoxy-substituted (NCN)-C-boolean AND-N-boolean AND ligand are the better emitters. Three examples of related complexes of the form Ir((NCN)-C-boolean AND-N-boolean AND)((NN-)-N-boolean AND)Cl - incorporating a bidentate 1,2,4-triazolylpyridine - have also been prepared. They show no room-temperature emission but the properties at 77 K are similar to those of the bis-tridentate systems.
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