期刊
INORGANIC CHEMISTRY
卷 61, 期 13, 页码 5326-5334出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c00074
关键词
-
资金
- National Natural Science Foundation of China [21801065, 21771057, U1804253]
In this study, the B(9)-H halogenation of o-carborane and m-carborane was achieved with excellent selectivities using hexafluor-oisopropanol as the solvent. The reaction conditions were simple and the use of a single reagent resulted in good yields of various halogenated products.
The B(9)-H halogenation of o-carborane and m-carborane was achieved with excellent selectivities in hexafluor-oisopropanol (HFIP) under simple reaction conditions: singlereagent [trichloroisocyanuric acid (TCCA), tribromoisocyanuricacid (TBCA) orN-iodosuccinimide (NIS)], catalyst-free, air-/moisture-tolerant, and convenient work-up. With this method, avariety of 9-halogenatedo-carboranes andm-carboranes were obtained in good to excellent yields with broad tolerance of functional groups
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据