期刊
INDUSTRIAL CROPS AND PRODUCTS
卷 179, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.indcrop.2022.114686
关键词
Cellulose nanocrystal (CNC); Cellulose nanofiber (CNF); Nanocomposite film; Transparency; Mechanical properties
资金
- National Natural Science Foundation of China [22078306]
- Key Research and Devel-opment Program of Zhejiang Province [2020C02021]
- Leading Goose R&D Program of Zhejiang Province [2022C01234]
- Natural Science Foundation of Zhejiang Province [LQ21C160006]
- Zhejiang Provincial General Scientific Research Projects Fund of China [Y202147666]
- 521 Talent Cultivation Program of Zhejiang Sci-Tech University [11110132521310]
In this study, nano composite films composed of cellulose nanofiber and cellulose nanocrystal were prepared via vacuum filtration method, and the effects of different ratios on the performance of the films were investigated. The results showed that an equal proportion of cellulose nanofiber and cellulose nanocrystal resulted in the optimal performance of the nano composite films.
Cellulose nanomaterials (CNs) are of increasing interest due to their appealing inherent properties and show great promise in various applications such as reinforcing agent and barrier membrane. In this work, nano composite films composed with cellulose nanofiber (CNF) and cellulose nanocrystal (CNC) were prepared via vacuum filtration method. The effects of CNF/CNC ratios on the rheological behavior of nanocomposite suspension as well as the transparency, barrier performance, mechanical properties and thermal stability of nanocomposite films were investigated, and the microstructure of nanocomposite films was characterized. The results indicated that equal proportion of CNF and CNC appeared to be the optimal state for nanocomposite film preparation, at which the nanocomposite films exhibited compact network structures, desired thermal stability, a tensile strength of 60.5 MPa, water vapor transmittance of 923.9 g/m(2)/24 h (38 C, 100% RH) and transparency of up to 92.7%. This work provides an effective and scalable approach for the preparation of nanocellulose based films with high performance, which may hold great promise in the biodegradable materials for advanced packaging applications.
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