Novel Ionic Liquid-Based Aqueous Biphasic System with Amino Acids for Critical Metal Recovery from Lithium-Ion Batteries

: The era of electric vehicles is rapidly approaching, and therefore, it is crucial to provide a sustainable technology for ensuring the circular economy of lithium-ion batteries. In this study, we report the development of a novel aqueous biphasic system (ABS) comprising fully biocompatible components, that is, hydrophilic ionic liquids, amino acids, and organic acids, for the selective recovery of Co(II) and Ni(II) from Mn(II), which are critical metals in spent lithium-ion batteries. Separation of Co(II), Ni(II), and Mn(II) from sulfate media was successfully carried out using the ABS in a quite straightforward manner without any hazardous reagents or organic solvents. In addition, the plausible mechanism of metal ion separation within the ABS was elucidated. The regenerated ionic liquid in the ABS exhibited remarkably stable performance during use in three consecutive experimental cycles.

Automated summary

This study reports the development of a novel aqueous biphasic system (ABS) for the selective recovery of critical metals Co(II) and Ni(II) from spent lithium-ion batteries. The ABS successfully separated Co(II), Ni(II), and Mn(II) without the use of hazardous reagents or organic solvents. The mechanism of metal ion separation within the ABS was elucidated, and the regenerated ionic liquid in the ABS exhibited remarkably stable performance.