4.7 Review

Research progress of natural gas hydrate exploitation with CO2 replacement: A review

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Characterizing Mass-Transfer mechanism during gas hydrate formation from water droplets

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Summary: The study investigated the mass-transfer characteristics of water and guest molecules in dense hydrate structures during formation from water droplets. Experimental results showed time-dependent 3D morphologies and parameters of hydrate shells, revealing a transition in the water transport schema within hydrate shells from diffusion to permeation. The effective diffusion coefficients of gas and water molecules in hydrates were quantified, providing fundamental insights for optimizing hydrate-based techniques.

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Kinetic study of methane hydrate development involving the role of self-preservation effect in frozen sandy sediments

Bo Li et al.

Summary: The study investigates the kinetic decomposition behaviors of methane hydrate below freezing point through experimental and numerical simulations. It is found that the modified new model considering the protection effect of ice predicts gas recovery and hydrate dissociation more accurately. The self-preservation effect is identified as the main factor leading to undesirable recovery efficiency of frozen gas hydrate, which can only be eliminated by external heat injection.

APPLIED ENERGY (2021)

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Replacement in CH4-CO2 hydrate below freezing point based on abnormal self-preservation differences of CH4 hydrate

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Summary: Utilizing multi-defective ice to construct porous CO2 hydrate can improve the efficiency of CH4-CO2 hydrate replacement, providing a new method for CH4 recovery and CO2 sequestration. Experimental results showed that the replacement efficiency at 272.15 K was significantly higher than at 268.15 K, confirming the feasibility of the replacement concept.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Engineering, Environmental

Pressure oscillation controlled CH4/CO2 replacement in methane hydrates: CH4 recovery, CO2 storage, and their characteristics

Lingjie Sun et al.

Summary: A method utilizing pressure oscillation during CH4/CO2 replacement is proposed in this study, which effectively promotes the replacement process by breaking the balance of the hydrate layer and forming a CO2/CH4 mixed hydrate layer. This newly proposed method significantly enhances the recovery of CH4 and the efficiency of CO2 sequestration.

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Influence of Competitive Inclusion of CO2 and N2 on sII Hydrate-Flue Gas Replacement for Energy Recovery and CO2 Sequestration

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

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Insights into the Control Mechanism of Heat Transfer on Methane Hydrate Dissociation via Depressurization and Wellbore Heating

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The use of sodium chloride as strategy for improving CO2/CH4 replacement in natural gas hydrates promoted with depressurization methods

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ARABIAN JOURNAL OF GEOSCIENCES (2020)

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Predictions on CH4 recovery factors using the CO2 replacement method to develop natural gas hydrate resources

Wenlong Jia et al.

JOURNAL OF CO2 UTILIZATION (2020)

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The second natural gas hydrate production test in the South China Sea

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CHINA GEOLOGY (2020)

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Recovering CH4 from natural gas hydrate with CO2 in porous media below the freezing point

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PETROLEUM SCIENCE AND TECHNOLOGY (2019)

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Strain Rate-Dependent Hardening-Softening Characteristics of Gas Hydrate-Bearing Sediments

C. Deusner et al.

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The mathematical model of the gas hydrate deposit development in permafrost

N. G. Musakaev et al.

INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER (2018)

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Submarine slope failures due to pipe structure formation

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Estimation of China's production efficiency of natural gas hydrates in the South China Sea

Zhaoyang Kong et al.

JOURNAL OF CLEANER PRODUCTION (2018)

Proceedings Paper Thermodynamics

Natural gas recovery from hydrate compounds using CO2 replacement strategies: experimental study on thermal stimulation

Gambelli Alberto Maria

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The first offshore natural gas hydrate production test in South China Sea

Jin-fa Li et al.

CHINA GEOLOGY (2018)

Article Thermodynamics

Theoretical research of the gas hydrate deposits development using the injection of carbon dioxide

V. Sh. Shagapov et al.

INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER (2017)

Article Chemistry, Physical

Diffusion Model for Gas Replacement in an Isostructural CH4-CO2 Hydrate System

A. N. Salamatin et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

Article Chemistry, Applied

Recovering methane from quartz sand-bearing hydrate with gaseous CO2

Shuanshi Fan et al.

JOURNAL OF ENERGY CHEMISTRY (2017)

Article Energy & Fuels

Gas production from hydrates by CH4-CO2/H2 replacement

Xiao-Hui Wang et al.

APPLIED ENERGY (2017)

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Enhanced CH4 recovery and CO2 storage via thermal stimulation in the CH4/CO2 replacement of methane hydrate

Lunxiang Zhang et al.

CHEMICAL ENGINEERING JOURNAL (2017)

Article Engineering, Environmental

CH4 - Flue gas replacement occurring in sH hydrates and its significance for CH4 recovery and CO2 sequestration

Yohan Lee et al.

CHEMICAL ENGINEERING JOURNAL (2017)

Review Energy & Fuels

Energy-efficient natural gas hydrate production using gas exchange

Dong-Yeun Koh et al.

APPLIED ENERGY (2016)

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Thermally Assisted Dissociation of Methane Hydrates and the Impact of CO2 Injection

Swanand S. Tupsakhare et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2016)

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Simulation of CO2 storage and methane gas production from gas hydrates in a large scale laboratory reactor

Beatrice Castellani et al.

JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING (2016)

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Molecular Mechanisms of Gas Diffusion in CO2 Hydrates

Shuai Liang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2016)

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Direct transition mechanism for molecular diffusion in gas hydrates

A. Vidal-Vidal et al.

RSC ADVANCES (2016)

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Guest Migration Revealed in CO2 Clathrate Hydrates

A. N. Salamatin et al.

ENERGY & FUELS (2015)

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Elastic properties of hydrate-bearing sandy sediment during CH4-CO2 replacement

Xiao-Hui Wang et al.

ENERGY CONVERSION AND MANAGEMENT (2015)

Article Engineering, Environmental

Enhanced CH4 Recovery Induced via Structural Transformation in the CH4/CO2 Replacement That Occurs in sH Hydrates

Yohan Lee et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2015)

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A comparative analysis of the mechanical behavior of carbon dioxide and methane hydrate-bearing sediments

Masayuki Hyodo et al.

AMERICAN MINERALOGIST (2014)

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Replacement of Methane from Hydrates in Porous Sediments with CO2-in-Water Emulsions

Qing Yuan et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2014)

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Nondestructive natural gas hydrate recovery driven by air and carbon dioxide

Hyery Kang et al.

SCIENTIFIC REPORTS (2014)

Article Chemistry, Applied

Molecular dynamics simulations for the growth of CH4-CO2 mixed hydrate

Lizhi Yi et al.

JOURNAL OF ENERGY CHEMISTRY (2014)

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Thermodynamic and 13C NMR spectroscopic verification of methane-carbon dioxide replacement in natural gas hydrates

Seungmin Lee et al.

CHEMICAL ENGINEERING JOURNAL (2013)

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Methane recovery from natural gas hydrate in porous sediment using pressurized liquid CO2

Qing Yuan et al.

ENERGY CONVERSION AND MANAGEMENT (2013)

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Kinetics of CO2-Hydrate Formation from Ice Powders: Data Summary and Modeling Extended to Low Temperatures

A. Falenty et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

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Experimental measurements of mechanical properties of carbon dioxide hydrate-bearing sediments

Weiguo Liu et al.

MARINE AND PETROLEUM GEOLOGY (2013)

Article Geosciences, Multidisciplinary

Review of progress in evaluating gas hydrate drilling hazards

Daniel R. McConnell et al.

MARINE AND PETROLEUM GEOLOGY (2012)

Article Thermodynamics

Molecular dynamics simulation of replacement of CH4 in hydrate with CO2

Yingxia Qi et al.

ENERGY CONVERSION AND MANAGEMENT (2011)

Article Green & Sustainable Science & Technology

P-wave monitoring of hydrate-bearing sand during CH4-CO2 replacement

D. Nicolas Espinoza et al.

INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL (2011)

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The Conversion Process of Hydrocarbon Hydrates into CO2 Hydrates and Vice Versa: Thermodynamic Considerations

J. M. Schicks et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2011)

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Complementary imaging of oil recovery mechanisms in fractured reservoirs

G. Ersland et al.

CHEMICAL ENGINEERING JOURNAL (2010)

Article Geochemistry & Geophysics

CH4-CO2 replacement in hydrate-bearing sediments: A pore-scale study

J. W. Jung et al.

GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS (2010)

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Using magnetic resonance imaging to monitor CH4 hydrate formation and spontaneous conversion of CH4 hydrate to CO2 hydrate in porous media

Bernard A. Baldwin et al.

MAGNETIC RESONANCE IMAGING (2009)

Article Energy & Fuels

Swapping phenomena occurring in deep-sea gas hydrates

Kyuchul Shin et al.

ENERGY & FUELS (2008)

Article Thermodynamics

Determination of appropriate condition on replacing methane from hydrate with carbon dioxide

Xitang Zhou et al.

ENERGY CONVERSION AND MANAGEMENT (2008)

Article Chemistry, Multidisciplinary

Path Sampling Calculation of Methane Diffusivity in Natural Gas Hydrates from a Water-Vacancy Assisted Mechanism

Baron Peters et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

Article Engineering, Chemical

Macro and microscopic CH4-CO2 replacement in CH4 hydrate under pressurized CO2

Masaki Ota et al.

AICHE JOURNAL (2007)

Article Chemistry, Physical

Free energies of carbon dioxide sequestration and methane recovery in clathrate hydrates

Peter Dornan et al.

JOURNAL OF CHEMICAL PHYSICS (2007)

Article Multidisciplinary Sciences

Sequestering carbon dioxide into complex structures of naturally occurring gas hydrates

Youngjune Park et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2006)

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The phase-field theory applied to CO2 and CH4 hydrate

A Svandal et al.

JOURNAL OF CRYSTAL GROWTH (2006)

Article Thermodynamics

Replacement of CH4 in the hydrate by use of liquid CO2

M Ota et al.

ENERGY CONVERSION AND MANAGEMENT (2005)

Article Thermodynamics

Methane recovery from methane hydrate using pressurized CO2

M Ota et al.

FLUID PHASE EQUILIBRIA (2005)

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Transformation of methane hydrate to carbon dioxide hydrate: In situ Raman spectroscopic observations

JH Yoon et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2004)

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Fundamental principles and applications of natural gas hydrates

ED Sloan

NATURE (2003)

Article Chemistry, Multidisciplinary

Recovering methane from solid methane hydrate with carbon dioxide

H Lee et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)