Development of novel composite rejuvenators for efficient recycling of aged SBS modified bitumen

Efficient recycling of aged SBS modified bitumen (ASBS-MB) is one of the difficult problems in the field of pavement materials. In this study, isocyanate terminated long chain active rejuvenators (ITLCARs) for aged SBS were synthesized by the reaction of 2,4-toluylene diisocyanate (TDI)/ hexamethylene diisocyanate (HDI) and hydroxyl terminated polybutadiene (HTPB), namely T-HTPB and H-HTPB. And T-HTPB/H-HTPB and aromatic hydrocarbon oil (AO) were combined to form novel composite rejuvenators (NCRs), which were used to restore the properties of ASBS-MB. Afterwards, the effects of NCRs on physical properties, rheological properties and molecular weight distribution of ASBS-MB were investigated. FTIR results showed that ITLCARs were successfully synthesized. The results of gel permeation chromatography showed that NCRs had advantages in restoring the molecular weight of ASBS-MB to the level of SBS-MB. And the physical performances of ASBS-MB could be regenerated to the level of original SBS modified bitumen (SBS-MB) by NCRs. The high-temperature complex modulus and rutting factor of rejuvenated SBS modified bitumen (RSBS-MB) recovered by NCRs were better than those restored only by AO. Meanwhile, the low-temperature complex modulus and fatigue factor of RSBS-MB recovered by NCRs still had greater low-temperature properties. And the results of bending beam rheometer test indicated that creep stiffness and m-value of RSBS-MB at-12 degrees C and-18 degrees C meet the requirements of Strategic Highway Research Program. This study provides a novel rejuvenation method for the efficient recycling of ASBS-MB.

Automated summary

Efficient recycling of aged SBS modified bitumen (ASBS-MB) is a difficult problem in pavement materials. In this study, novel composite rejuvenators (NCRs) were synthesized using isocyanate terminated long chain active rejuvenators (ITLCARs) and aromatic hydrocarbon oil (AO) to restore the properties of ASBS-MB. The results showed that NCRs successfully restored the molecular weight and physical properties of ASBS-MB to the level of original SBS modified bitumen (SBS-MB). The high-temperature and low-temperature properties of the rejuvenated SBS modified bitumen (RSBS-MB) recovered by NCRs were better than those restored only by AO.