期刊
FOOD CHEMISTRY
卷 380, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2021.131852
关键词
MAILLARD reaction; Melanoidins; Heterocyclic intermediates; Mass spectrometry; Aldol reaction; Short-chain carbonyls
This study investigates the reaction between norfuraneol and different carbonyl compounds, as well as the underlying mechanisms. The results show that aldol reactions lead to the formation of carbohydrate-based oligomers, and redox reactions result in an increase in double bonds.
In the course of the MAILLARD reaction, reducing sugars and amino compounds are converted to colorants, whose chemical structures are still mostly unknown. Active methylene compounds like norfuraneol that can initiate aldol condensation reactions are considered as key intermediates in this reaction. The aim of the present study was to characterize color formation of norfuraneol with different carbonyl compounds and to identify the underlying mechanisms of the reaction. Norfuraneol was incubated with methylglyoxal or diacetyl at elevated temperatures and the resulting reaction mixtures were analyzed by means of high-resolution mass spectrometry. It was demonstrated that aldol reactions lead to the formation of heterogeneous carbohydrate-based oligomers, which are likely to contribute to the elevated browning observed in the reaction mixtures. Furthermore, redox reactions were identified as another important part of the reaction, resulting in an increasing number of double bonds in the detected reaction products.
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