期刊
FLUID PHASE EQUILIBRIA
卷 556, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.fluid.2022.113414
关键词
Superbase salt; Ionic liquid; Cellulose dissolution; Liquid-liquid extraction; Physicochemical properties
资金
- Bio-Based Industries Joint Undertaking under the European Union's Horizon 2020 research and innovation program [837527-GRETE -H2020-BBI-JTI-2018]
- Foundation for Science and Technology/MCTES [UIDB/50011/2020, UIDP/50011/2020]
- National NMR Network [REDE/1517/RMN/2005]
- POCI 2010 (FEDER)
- FCT
This study aims to characterize the physicochemical properties of binary systems of water and two superbase-based ionic liquids, and to experimentally screen potential extractants for the recovery of the ILs. The results show that butanol has a certain extraction efficiency for [mTBDH][OAc].
Superbase-based ionic liquids 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-enium acetate, [mTBDH][OAc], and 5-methyl-1,5,7-triaza-bicyclo[4.3.0]non-6-enium acetate, [mTBNH][OAc], are good candidates to produce high performance cellulose fibres while presenting much easy spinnability and good recyclability, than the state-of-the-art ionic liquids. Nevertheless, the recovery of the IL from the aqueous spinning bath and its purification, which are both an economical and environmental necessity, are important aspects that are still not solved. Aiming to gather knowledge to recover and recycle superbase-ILs, the main goal of this work is the physicochemical characterization of the binary systems water + [mTBDH][OAc] or [mTBNH][OAc]. Measurements performed include solid-liquid equilibria, vapor-liquid equilibria, water activity, Kamlet -Taft solvatochromic parameters, densities, and viscosities. An experimental screening on possible hydrophobic extractants for the recuperation of the ionic liquids from aqueous solution was performed. Using butanol, an extraction efficiency of 37% for [mTBDH][OAc] was achieved. Better extraction efficiencies were achieved with chlorinated solvents, however, they seem to react with the ILs anion. (C) 2022 Elsevier B.V. All rights reserved.
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