期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2022, 期 22, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202200276
关键词
Group transfer reactions; Heterocycles; Hypervalent compounds; Iodonium salts; Synthetic methods
资金
- Projekt DEAL
This study presents a systematic investigation of ethynyl N-heterocycle-substituted-lambda(3)-iodanes (ENHIs) and evaluates their potential applications in alkyne group transfer reactions through synthesis and reactivity assessment.
A systematic investigation of ethynyl N-heterocycle-substituted-lambda(3)-iodanes (ENHIs) is presented. In a straightforward one-pot synthesis these novel reagents can be obtained in high yields bearing a variety of N-heterocycles. Their reactivity as electrophilic alkyne group transfer reagents was benchmarked in well-established and novel inter- and intramolecular group transfer reactions.
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