4.5 Article

A Stable and Photoreactive Copper-Iodide Cubane Suitable for Direct Post-Functionalization

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出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202200101

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Copper; Coordination chemistry; Luminescence; Phosphine ligands; Reactivity

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  1. Region Grand Est (France)
  2. Clariant (Muttenz, Switzerland)

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A tetranuclear copper-iodide cluster has been identified as a stable precursor for further post-functionalization, allowing the direct functionalization of alkenes and providing access to a wide range of luminescent copper cubane complexes, including the first example of water-soluble luminescent cubane copper iodide.
Tetranuclear copper-iodide cluster consisting of a {Cu4I4} cubane and diphenylphosphine ligand has been found as a highly stable precursor for further post-functionalization through hydrophosphination reaction. UV irradiation of the cluster in the presence of various alkenes allows direct functionalization of the latter, giving access to a wide range of copper cubane complexes, a source of molecular diversity for luminescent materials. Such a strategy provided access to the first example of water-soluble luminescent cubane copper iodide.

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