期刊
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 -, 期 -, 页码 -出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11356-022-19326-4
关键词
Solid-state ion exchange adsorption; Surfactant; Modified bentonite with iron; Photo-Fenton
A new adsorbent was synthesized using ion-exchange, which showed high adsorption rate for methyl orange dye and agreed with pseudo-second-order model and Langmuir equation.
A new adsorbent was synthesized using ion-exchange between iron salts and bentonite modified with acetyl trimethylammonium bromide (CTAB) in the solid phase. Ion-exchange was performed in the solid state at a temperature of 100 degrees C for 2 min. Various analyses such as X-ray diffraction (XRD), scanning electron microscopy (SEM), porosity measurement (BET), infrared Fourier transform (FT-IR), transmission electron microscopy (TEM), X-ray energy diffraction (EDX), and thermal weighing (TGA) were used to characterize the synthesized nano-adsorbents. Under optimal conditions (pH = 7, time 60 min, concentration of dye solution 150 ppm, and amount of nano-adsorbent 0.75 g/l), the modified nano-adsorbent absorbed 73% of the methyl orange (MO) dye. Adsorption isotherm studies and kinetic model showed that the pseudo-second-order model and Langmuir equation agree with the obtained results. After three reductions of the modified nano-adsorbent in the photo-Fenton process, the dye absorption percentage was 69.50%.
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