期刊
ENVIRONMENTAL SCIENCE & TECHNOLOGY
卷 56, 期 7, 页码 3960-3973出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.est.1c07691
关键词
air pollution; phase separation; organic aerosol particles; human health; oxygen-to-carbon ratio; secondary organic aerosol
资金
- European Union [890200]
- Natural Sciences and Engineering Research Council of Canada (NSERC) [RGPIN/044412016]
- Work Lean International Undergraduate Research [111108]
- Harvard University Center for the Environment through the Environmental Fellows program
- Environmental Chemical Sciences of the Division of Chemistry of the U.S. National Science Foundation [ECS2003368]
- Marie Curie Actions (MSCA) [890200] Funding Source: Marie Curie Actions (MSCA)
The phase behavior of atmospheric particles containing mixtures of hydrocarbon-like organic aerosol (HOA) and secondary organic aerosol (SOA), which is determined by the difference in the average oxygen-to-carbon atomic ratio, is important for predicting their impacts on air pollution, human health, and climate. This study found that 88% of the 77 different HOA + SOA mixtures studied exhibited two phases. The phase behavior was independent of relative humidity but correlated with the difference in O/C ratios between the HOA and SOA components.
The phase behavior, the number and type of phases, in atmospheric particles containing mixtures of hydrocarbon-like organic aerosol (HOA) and secondary organic aerosol (SOA) is important for predicting their impacts on air pollution, human health, and climate. Using a solvatochromic dye and fluorescence microscopy, we determined the phase behavior of 11 HOA proxies (O/C = 0-0.29) each mixed with 7 different SOA materials generated in environmental chambers (O/C 0.4-1.08), where O/C represents the average oxygen-to-carbon atomic ratio. Out of the 77 different HOA + SOA mixtures studied, we observed two phases in 88% of the cases. The phase behavior was independent of relative humidity over the range between 90% and <5%. A clear trend was observed between the number of phases and the difference between the average O/C ratios of the HOA and SOA components (Delta O/C). Using a threshold Delta O/C of 0.265, we were able to predict the phase behavior of 92% of the HOA + SOA mixtures studied here, with one-phase particles predicted for Delta O/C < 0.265 and two-phase particles predicted for Delta O/C >= 0.265. The threshold Delta O/C value provides a relatively simple and computationally inexpensive framework for predicting the number of phases in internal SOA and HOA mixtures in atmospheric models.
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