Effect of magnetization on the adsorptive removal of an emerging contaminant ciprofloxacin by magnetic acid activated carbon

Magnetic acid activated carbons (MAAC) were prepared from the shells of Sterculia villosa Roxb by activating the biomass and magnetizing it using the co-precipitation technique. Characterization of MAAC prior and post adsorption was performed using various microscopic and spectroscopic analytical techniques, and they verified the formation of magnetic aggregates over porous activated carbon surface. Vibrating Sample Magnetometer (VSM) analysis confirmed the superparamagnetic behaviour of the adsorbent with saturation magnetization (Ms) value of 18.2 emu/g, causing an easy and rapid recovery from the adsorption setup in the presence of an external magnetic field. Langmuir isotherm and pseudo-second-order kinetic model best fit the experimental data with theoretical Langmuir maximum adsorption capacity as 81.97 mg/g and verifying chemisorption type of adsorption process, respectively. Thermodynamic analysis verified the interaction among adsorbate and adsorbent as endothermic, spontaneous, and thermodynamically favourable. Co-existing metal cations showed a significant reduction in cipmfloxacin removal efficiency; co-existing anions, though, showed a negligible influence on the adsorption efficiency of MAAC. Recyclability studies verified that the adsorption efficiency fell from 98% in the first cycle to 43% in the fifth cycle. The Ms value fell to 7.6 emu/g (after five adsorption cycles), affecting the adsorbent's recovery. The Phyto-toxicological assessment was performed to evaluate the environmental risk to human and aquatic life using Vigna mango seeds. MAAC proved to be an effective and magnetically separable adsorbent for removing antibiotics.

Automated summary

The study prepared magnetic acid activated carbons from Sterculia villosa Roxb shells and characterized them before and after adsorption, confirming the formation of magnetic aggregates. Experimental data fit Langmuir isotherm and pseudo-second-order kinetic model, while thermodynamic analysis showed the adsorption process to be endothermic, spontaneous, and thermodynamically favorable.