Source and enrichment mechanism of fluoride in groundwater of the Hotan Oasis within the Tarim Basin, Northwestern China

In arid inland irrigated areas, the role of human activities on fluoride enrichment in groundwater is not fully understood. There is an extremely arid climate, high-intensity irrigation, and severe soil salinization in the Hotan Oasis within the Tarim Basin, Northwestern China. In this study, hydrogeochemistry and environmental isotope methods were combined to explore the distribution characteristics and controlling processes of fluoride enrichment in groundwater. The F- concentration in groundwater had a range of 1.12-9.4 mg/L. F- concen trationsof all the groundwater samples were higher than 1.0 mg/L (Chinese Standards for Drinking Water Quality), and about 89% were higher than 1.5 mg/L (WHO Guidelines for Drinking Water Quality). High fluoride groundwater was mainly distributed downstream of the river and in the middle of the interfluvial zone. Vertically, the fluoride concentration was higher when the sampling depth was less than 15 m. There was a significant positive correlation between F- concentration and salinity in groundwater. F- in groundwater was mainly derived from river water fluoride, which could be imported to groundwater with infiltration of rivers and irrigation canals as well as irrigation return flow. Anthropogenic inputs may be partly responsible for fluoride enrichment in groundwater. Fluoride accumulated in the vadose zone by strong evapotranspiration and then leached into groundwater with irrigation return flow was the main mechanism of F- enrichment in groundwater in the study area. This work is a clear example of how human activities together with natural processes can affect the chemical quality of groundwater, which is essential to safeguard the sustainable management of water and soil resources inland arid oasis areas.

Automated summary

This study investigated the distribution characteristics and controlling processes of fluoride enrichment in groundwater in arid inland irrigated areas. The results showed that fluoride concentration in groundwater was generally high and positively correlated with salinity. River water was identified as the main source of fluoride in groundwater, and anthropogenic inputs were found to contribute to fluoride enrichment.