4.7 Article

Siderite/Concrete catalysts for H2-enriched gas production from biomass steam gasification

期刊

ENERGY CONVERSION AND MANAGEMENT
卷 255, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.enconman.2022.115280

关键词

Biomass; Gasification; Catalyst; Siderite; Concrete

资金

  1. project NOTARGAS [POCI-01-0145-FEDER-030661]
  2. project SusPhotoSolutions -Solucoes Fotovoltaicas Sustentaveis, PO Centro 2020 [CENTRO-01-0145-FEDER-000005]
  3. Portuguese Foundation for Science and Technology (FCT)/Ministry of Science, Technology and Higher Education (MCTES) [UIDP/50017/2020+UIDB/50017/2020+LA/P/0094/2020, UIDB/50011/2020, UIDP/50011/2020]
  4. Portuguese Foundation for Science and Technology [SFRH/BD/129901/2017, 2020.09864.BD]
  5. Fundação para a Ciência e a Tecnologia [2020.09864.BD, SFRH/BD/129901/2017] Funding Source: FCT

向作者/读者索取更多资源

This study proposes the use of granulated siderite/concrete-based catalysts for biomass steam gasification, aiming to enrich H-2 by water gas shift and CO2 adsorption. The impact of reaction temperature, concrete/siderite ratio, and steam to carbon molar ratio on H-2 promotion is investigated. The catalyst shows high activity when integrated into a bubbling fluidized bed gasifier. However, repeated cycles of regeneration result in a gradual decrease in activity.
In this study, granulated siderite/concrete-based catalysts are proposed for in-situ applications in biomass steam gasification, seeking H-2-enrichement by the contribution of water gas shift and CO2 adsorption. A cost-effective procedure has been applied for the preparation of granulated catalysts. Water Gas Shift reaction was studied in a fixed bed reactor and Taguchi experimental design was used to elucidate the relevance of experimental parameters on catalyst performance. The results show that the impact of reaction temperature, concrete/siderite ratio and steam to carbon molar ratio on H-2 promotion had the following order: reaction temperature (43.1%), concrete/siderite ratio (30.2%) and steam to carbon molar ratio (26.7%). Additionally, the catalyst exhibited high activity when integrated into the freeboard zone of a bubbling fluidized bed gasifier. Compared to the reference condition, one observed significant impact at 700 C on the H-2:CO ratio (1.9 to 3.3), H-2 production (33.8 to 48.6 gH(2) & BULL;kg(dry,fuel)(-1)), carbon conversion efficiency (54.1 to 58.6%) and cold gas efficiency (55.0 to 60.9%). Though the catalyst exhibited resistance to sintering, post-mortem analysis suggests loss of active species after repeated cycles of regeneration due to thermal-induced stresses, which caused gradual decrease in activity.

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