4.7 Article

Synthesis of Cobalt Diselenide Nanoparticles for the Integrated All-Solid-State Supercapacitors

期刊

ENERGY & FUELS
卷 36, 期 11, 页码 5928-5936

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.2c00545

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资金

  1. Natural Science Foundation of Hu'nan Province [2021JJ30708]
  2. Postgraduate Scientific Research Innovation project of Hu'nan Province [CX20200903]

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In this study, CoSe2 nanoparticles were synthesized and used as electrodes in supercapacitors. The CoSe2 nanoparticles exhibited excellent specific capacitance and stability, and showed typical voltage extension and charge/discharge time expansion capabilities in an asymmetric solid-state supercapacitor.
The operating voltage and current through integrated devices are effective ways to explore the practical applications of supercapacitors. In this study, CoSe2 nanoparticles were fabricated by a facile hydrothermal method. As supercapacitor electrodes, CoSe2 nanoparticles exhibited a specific capacitance of 389.6 F g-1 at 1 A g-1. When CoSe2 served as a positive electrode for the asymmetric solid-state supercapacitor, it presented 47.4 F g-1 specific capacitance, 46.4 Wh kg-1 energy density with 1512 W kg-1 power density, and superior stability (92.06% capacitance retention after 3000 cycles). Especially, the integrated all-solid-state supercapacitors connected in series displayed the typical voltage extension capability (2.8 V for two devices in series), and the ones in parallel exhibited charge/discharge time expand capabilities (390 s for two devices in parallel). Therefore, the study shows the promising practical applications of CoSe2based supercapacitors for energy storage.

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