☆ 4.7 Review

Recent Advances in Nanoscale Engineering of Ternary Metal Sulfide-Based Heterostructures for Photocatalytic Water SplittingApplications

ENERGY & FUELS (2022)

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Article Engineering, Environmental

In-situ Mo doped ZnIn2S4 wrapped MoO3 S-scheme heterojunction via Mo-S bonds to enhance photocatalytic HER

Hang Su et al.

Summary: A direct Step-scheme heterostructure of in-situ Mo doped ZnIn2S4 wrapped MoO3 (MoO3@Mo-ZIS) was prepared in this study, and it exhibited excellent photocatalytic activity. The enhanced H-2 evolution rate of the photocatalyst was attributed to the Mo doping and formation of Mo-S species. The direct S-scheme heterojunction of MoO3@Mo-ZIS promoted photogenerated carrier separation and improved the performance of photocatalytic hydrogen evolution reaction.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Energy & Fuels

Ultrafast Charge Separation in Ternary V2O5/CdS/CoS2 Z-Scheme Heterojunction Enables Efficient Visible-Light-Driven Hydrogen Generation

Shiwei Sun et al.

Summary: This study reports the synthesis and mechanistic studies of a newly designed Z-scheme ternary photocatalyst VCC. The VCC heterostructure exhibits excellent photocatalytic hydrogen evolution rate and stability, attributed to the ultrafast charge separation process. This work provides a new strategy to enhance photocatalytic performance and stability, as well as unravels the structure-property-function relationship in Z-scheme ternary structures.

ENERGY & FUELS (2022)

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Article Energy & Fuels

Rational Design of a Novel S-Scheme Heterojunction based on ZIF-67-Supported Ni-Fe Layered Double Hydroxide for Efficient Photocatalytic Hydrogen Generation

Kai Wang et al.

Summary: Metal-organic frameworks and layered double hydroxides have shown great potential in the field of photocatalytic hydrogen evolution due to their rich variety of structure and superior performance. However, it is challenging to achieve efficient charge separation with a single material, and heterojunction design is an effective strategy for constructing efficient photocatalysts. In this study, a ZIF-67@Ni-Fe LDH S-scheme heterojunction photocatalyst was successfully prepared and demonstrated efficient utilization of photogenerated electrons.

ENERGY & FUELS (2022)

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Article Chemistry, Physical

MoS2/HCSs/ZnIn2S4 nanocomposites with enhanced charge transport and photocatalytic hydrogen evolution performance

Yifeng Xu et al.

Summary: The study introduced the successful loading of MoS2 and HCSs on ZnIn2S4 nanosheets to form ternary nanocomposites, demonstrating superior photocatalytic hydrogen evolution activity with the highest hydrogen evolution rate of approximately 620.9 µmol g(-1) h(-1). The improvement was attributed to increased visible-light absorption, faster carrier transfer, and reduced electron-hole recombination.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Article Chemistry, Physical

The construction of three-dimensional CdIn2S4/MoS2 composite materials for efficient hydrogen production

Minghui Yu et al.

Summary: In this study, a CdIn2S4/MoS2 composite structure was prepared via a simple two-step hydrothermal synthesis method, leading to improved photocatalytic performance under visible light irradiation. The effective loading of MoS2 on CdIn2S4 particles inhibited the recombination of photogenerated electron holes, increasing visible light response and prolonging the life of photoexcitation carrier. The composite sample with 9% MoS2 content showed the highest catalytic hydrogen production activity, with a hydrogen production rate more than 3 times that of another sample, showing stable photocatalytic activity after multiple cycles.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Article Chemistry, Physical

Nickel clusters accelerating hierarchical zinc indium sulfide nanoflowers for unprecedented visible-light hydrogen production

Jun Chen et al.

Summary: In this study, Ni clusters were in-situ photodeposited in hierarchical ZnIn2S4 nanoflowers to enhance the photocatalytic hydrogen production. The Ni/ZnIn2S4 composites showed improved stability and reusability, with a significantly higher hydrogen production rate compared to pure ZnIn2S4. The depositing of non-precious Ni clusters in ZnIn2S4 is highly promising for practical photocatalysis in solar energy conversion.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Multidisciplinary Sciences

Insights from density functional theory calculations on heteroatom P-doped ZnIn2S4 bilayer nanosheets with atomic-level charge steering for photocatalytic water splitting

Wei-Kean Chong et al.

Summary: This study investigates the effects of phosphorus doping on ZnIn2S4 and reveals that phosphorus doping can enhance the photocatalytic water splitting performance. The findings provide important insights for the development of efficient solar water splitting photocatalysts.

SCIENTIFIC REPORTS (2022)

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Article Chemistry, Physical

Enhancing the photocatalytic activity of Ruddlesden-Popper Sr2TiO4 for hydrogen evolution through synergistic silver doping and moderate reducing pretreatment

Hongbo Xiao et al.

Summary: In this study, silver-doped and moderately reduced Sr2TiO4 photocatalysts were synthesized, showing improved morphological characteristics and enhanced hydrogen generation performance.

MATERIALS TODAY ENERGY (2022)

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Article Chemistry, Physical

Non-metal fluorine doping in Ruddlesden-Popper perovskite oxide enables high-efficiency photocatalytic water splitting for hydrogen production

Xiao Han et al.

Summary: In this study, a non-metal fluorine (F-) doping strategy was utilized to enhance the photocatalytic activity of Ruddlesden-Popper Sr2TiO4 perovskites for H-2 evolution reaction (HER). By optimizing the F- doping amount, the highest H2 generation rate was achieved by Sr2TiO3.97F0.03, which showed a 44% enhancement compared to Sr2TiO4. The improved photocatalytic activity of Sr2TiO3.97F0.03 can be attributed to the effects of F- doping on surface oxygen vacancies, charge carrier recombination, conduction band position, band gap energy, particle size, and specific surface area.

MATERIALS TODAY ENERGY (2022)

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Article Chemistry, Multidisciplinary

Efficient charge separation in hierarchical NiS@ZnIn2S4 hollow nanospheres for photocatalytic water splitting

Kai Wu et al.

Summary: In this study, a hierarchical NiS@ZIS heterostructure was developed for photocatalytic water splitting to produce hydrogen. The NiS@ZIS exhibited strong optical absorption and high specific surface area in the visible region, and achieved efficient hydrogen production under visible light.

CHINESE CHEMICAL LETTERS (2022)

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Review Energy & Fuels

Photocorrosion inhibition of sulphide-based nanomaterials for energy production through photocatalytic water splitting

Sara Yaseen et al.

Summary: This review discusses the potential role of sulphide-based nanomaterial photocatalysts in addressing energy, global warming, and environmental issues. While these photocatalysts show excellent performance in visible light, they are susceptible to photocorrosion and require surface modifications to enhance stability.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2022)

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Review Chemistry, Physical

A mini-review on ZnIn2S4-Based photocatalysts for energy and environmental application

Guping Zhang et al.

Summary: Semiconductor photocatalysis is considered as an attractive and eco-friendly technology for addressing global energy shortage and environmental pollution. Zinc indium sulfide (ZnIn2S4) has gained research attention due to its excellent visible light absorption, high chemical durability, and low cost. However, the photocatalytic activity of pristine ZnIn2S4 is limited by its narrow visible light absorption range and fast recombination rate of electrons and holes. Various modification strategies have been developed to enhance the photocatalytic performance of ZnIn2S4 materials. This review summarizes recent progress in the construction of highly active ZnIn2S4-based photocatalysts and critically reviews their applications in hydrogen evolution, carbon dioxide photoreduction, and water pollution treatment. The current challenges and future prospects for ZnIn2S4 semiconductor photocatalysts are also discussed.

GREEN ENERGY & ENVIRONMENT (2022)

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Article Nanoscience & Nanotechnology

Tuning the Crystallinity and Coverage of SiO2-ZnIn2S4 Core-Shell Nanoparticles for Efficient Hydrogen Generation

Mrinalini Mishra et al.

Summary: By adding acid in ethanol, the crystallinity of SiO2@ZIS core-shell nanoparticles can be improved, and the thickness of the ZIS shell can be controlled by adjusting the amount of acid and the concentration of the ZIS precursor.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Energy & Fuels

g-C3N4/α-Fe2O3 Supported Zero-Dimensional Co3S4 Nanoparticles Form S-Scheme Heterojunction Photocatalyst for Efficient Hydrogen Production

Teng Yan et al.

Summary: The study prepared an S-type heterojunction photocatalyst with excellent photoelectrochemical performance and stability, achieving significantly higher hydrogen evolution amount compared to pure Co3S4. The performance improvement of the composite material can be attributed to the role of EY molecules, highly dispersed Co3S4 nanoparticles, and the constructed S-scheme heterojunction that promotes carrier separation.

ENERGY & FUELS (2021)

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Article Energy & Fuels

Anchoring Iron Oxides on Carbon Nitride Nanotubes for Improved Photocatalytic Hydrogen Production

Amanj Kheradmand et al.

Summary: This study utilized photocatalytic nanocomposites to generate hydrogen, with Fe3O4/C3N4NTs showing the highest photocatalytic performance and stability. Compared to Fe2O3/C3N4NTs, Fe3O4/C3N4NTs had a higher utilization of visible-light radiation and more efficient electron-hole pair separation.

ENERGY & FUELS (2021)

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Article Chemistry, Physical

Synthesis of CaIn2S4/TiO2 heterostructures for enhanced UV-visible light photocatalytic activity

Ping Zhang et al.

Summary: Semiconductor heterostructures, such as the novel Z-scheme CaIn2S4 (CIS)/TiO2 photocatalysts, show improved photocatalytic activity due to increased light absorption and reduced electron-hole recombination. The intimate contact and matched energy band positions between CIS and TiO2 efficiently produce active charge carriers, reducing recombination and boosting carrier transfer. The proposed Z-scheme mechanism provides insights for designing high-efficiency heterojunction photocatalysts for photodegradation applications.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Physical

Au nanodots@thiol-UiO66@ZnIn2S4 nanosheets with significantly enhanced visible-light photocatalytic H2 evolution: The effect of different Au positions on the transfer of electron-hole pairs

Siman Mao et al.

Summary: A new type of photocatalyst, Au@UiOS@ZIS, has been elaborately designed for efficient photocatalytic H-2 production, showing significantly higher activity compared to other single-component catalysts.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Engineering, Environmental

Controllable construction of hierarchically CdIn2S4/CNFs/Co4S3 nanofiber networks towards photocatalytic hydrogen evolution

Shuaiwei Guo et al.

Summary: Efficient charge separation and impeccable active sites are essential for hydrogen evolution from solar-driven water splitting. In this study, a novel 1D-2D CdIn2S4/CNFs/Co4S3 tandem Schottky heterojunction was synthesized, leading to exceptional H2 production activity and photostability, showcasing a promising avenue for high-efficiency photocatalysis.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Materials Science, Multidisciplinary

Synthesis of core-shell SnS2/CdIn2S4 heterojunction photocatalyst for visible light driven hydrogen evolution

Tuoya Wu Ren et al.

Summary: The core-shell SnS2/CdIn2S4 heterojunction was successfully synthesized through in-situ synthesis of SnS2 nanosheets on CdIn2S4 nanoflower. The composites have larger specific surface area and more reactive sites, leading to improved photocatalytic activity. CIS/S-11 showed the highest photocatalytic activity rate of 345.2 mu mol/g/h, indicating significantly enhanced efficiency of photocatalytic hydrogen production compared to pristine CdIn2S4.

MATERIALS LETTERS (2021)

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Article Chemistry, Physical

2D β-NiS as electron harvester anchors on 2D ZnIn2S4 for boosting photocatalytic hydrogen production

Liang Ding et al.

Summary: The study successfully synthesized a NiS/ZnIn2S4 heterojunction with a well-constructed integrated structure, which significantly enhances the efficiency of photocatalytic hydrogen production and exhibits excellent stability.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Physical

A novel, noble-metal-free core-shell structure Ni-P@C cocatalyst modified sulfur vacancy-rich ZnIn2S4 2D ultrathin sheets for visible light-driven photocatalytic hydrogen evolution

Qi Ran et al.

Summary: The study demonstrates the enhanced photocatalytic activity and hydrogen production by introducing Ni-P@C cocatalyst and S-vacancy ZnIn2S4 (Vs-ZIS). Accelerating carrier transfer and increasing effective reaction sites lead to the development of Ni-P@C/Vs-ZIS-2 photocatalyst, showing superior performance in hydrogen evolution. This approach opens new opportunities for efficient hydrogen production.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Physical

Robust Co9S8@CdIn2S4 Cage for Efficient Photocatalytic H2 Evolution

Taraka Prabhu Yendrapati et al.

Summary: The Co9S8@CdIn2S4 hierarchical hollow heterostructure demonstrates enhanced light-harvesting ability and remarkable catalytic activity due to its distinctive structural and compositional advantages. The photocatalyst achieves a high hydrogen evolution rate without noble metal cocatalysts, showcasing the successful interface of two-dimensional ultrathin subunits with intriguing photophysical properties.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Article Engineering, Chemical

Construction of zinc-indium-sulfide/indium oxide step-scheme junction catalyst for enhanced photocatalytic activities of pollutant degradation and hydrogen generation

Xuejun Zou et al.

Summary: A novel zinc-indium-sulfide/indium oxide photocatalyst was prepared via a hydrothermal method and low temperature self-assembly process, showing enhanced photocatalytic activity for contaminants degradation and hydrogen production. The formation of a step-scheme junction hybrid system led to improved light absorption efficiency and charge separation efficiency, resulting in a significant H-2 yield from water splitting. The proposed mechanism of the photocatalytic process on the ZnIn2S4/In2O3 step-scheme heterojunction was discussed based on the results.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Article Chemistry, Multidisciplinary

Spatially Separating Redox Centers and Photothermal Effect Synergistically Boosting the Photocatalytic Hydrogen Evolution of ZnIn2S4 Nanosheets

Man Wang et al.

Summary: Spatially separated loading of reductive and oxidative cocatalysts on ZnIn2S4 nanosheets was achieved through designing a ternary Co9S8@ZnIn2S4@PdS (CS@ZIS@PS) hollow tubular core-shell structure. This structure not only efficiently improved charge separation and accelerated surface reduction-oxidation kinetics, but also generated a photothermal effect to further enhance charge transfer and surface reaction kinetics. The optimized CS@ZIS@PS showed a remarkable H-2 evolution rate and apparent quantum efficiency, making it one of the highest values among ZnIn2S4 materials.

SMALL (2021)

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Review Chemistry, Physical

Hierarchical Ternary Sulfides as Effective Photocatalyst for Hydrogen Generation Through Water Splitting: A Review on the Performance of ZnIn2S4

Ravichandran Janani et al.

Summary: This review emphasizes the recent approaches in developing hierarchical ternary sulfide based photocatalysts, focusing on ZnIn2S4, for efficient hydrogen generation through photocatalytic water splitting. The electronic structure of ZnIn2S4 and various strategies to improve material efficiency for photocatalytic hydrogen generation are discussed. Recent progress on essential aspects such as light absorption, charge separation, and transport are also highlighted.

CATALYSTS (2021)

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Article Nanoscience & Nanotechnology

Reasonably Introduced ZnIn2S4@C to Mediate Polysulfide Redox for Long-Life Lithium-Sulfur Batteries

Zexian Zhang et al.

Summary: The newly synthesized ZnIn2S4@C structure, derived from a metal organic framework, has been shown to efficiently mediate lithium polysulfide conversion, improve sulfur utilization, and enhance the performance of lithium-sulfur batteries.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Ni1-xCoxSe2-C/ZnIn2S4 Hybrid Nanocages with Strong 2D/2D Hetero-Interface Interaction Enable Efficient H2-Releasing Photocatalysis

Yuguang Chao et al.

Summary: The design of Ni1-xCoxSe2-C/ZnIn2S4 hierarchical nanocages with 2D/2D hetero-interfaces significantly enhances the separation and transfer of photo-generated charge carriers, leading to remarkable H-2 releasing photocatalytic activity under visible light irradiation.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Physical

Construction of a novel electron transfer pathway by modifying ZnIn2S4 with α-MnO2 and Ag for promoting solar H2 generation

Xiufang Wang et al.

Summary: The study focused on utilizing ternary Ag/α-MnO2/ZnIn2S4 photocatalysts to achieve efficient hydrogen production through water splitting by solar energy. The composite catalysts demonstrated excellent photocatalytic activity driven by visible light, with a significantly higher H-2-production rate compared to pure ZnIn2S4. The photogenerated electron transfer mechanism was analyzed in detail, offering a novel strategy for designing highly active visible light photocatalysts for clean energy applications.

APPLIED SURFACE SCIENCE (2021)

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Article Chemistry, Multidisciplinary

CdIn2S4/In(OH)3/NiCr-LDH Multi-Interface Heterostructure Photocatalyst for Enhanced Photocatalytic H2 Evolution and Cr(VI) Reduction

Rao Fu et al.

Summary: In this study, CdIn2S4/In(OH)(3)/NiCr-LDH heterostructure photocatalysts were successfully synthesized via a simple hydrothermal method, displaying improved photocatalytic activity for both Cr(VI) removal and H2 evolution. The enhanced performance was attributed to the formation of multiple intimate-contact interfaces, facilitating carrier migration and improving the separation efficiency of photo-excited electrons and holes. This work demonstrates a facile and cost-effective strategy for the development of efficient photocatalysts for environmental remediation.

NANOMATERIALS (2021)

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Article Chemistry, Physical

One-pot sulfurized synthesis of ZnIn2S4/S,N-codoped carbon composites for solar light driven water splitting

Xiaojin Fu et al.

Summary: In this study, ZnIn2S4 modified with S,N-codoped carbon composites were successfully synthesized via a one-pot sulfurized route, exhibiting enhanced photocatalytic activity for water splitting. However, prolonged photo-corrosion led to a decline in the durability of the composite material for water splitting applications.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Chemistry, Physical

Interface engineering of Co9S8/CdIn2S4 ohmic junction for efficient photocatalytic H2 evolution under visible light

Chunxue Li et al.

Summary: This study presents a novel approach for the design and development of photocatalysts using interface engineering, successfully preparing a Co9S8/CdIn2S4 photocatalyst with a robust internal electric field for enhanced hydrogen evolution rate.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Physical

Visually resolving the direct Z-scheme heterojunction in CdS@ZnIn2S4 hollow cubes for photocatalytic evolution of H2 and H2O2 from pure water

Erhuan Zhang et al.

Summary: The study successfully constructed CdS@ZnIn2S4 hierarchical hollow photocatalysts with a highly efficient direct Z-scheme system, enabling the conversion of pure water into H2 and H2O2. This work provides an effective approach for building efficient sulfide-only photocatalysts.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Physical

Direct Z-scheme TiO2-ZnIn2S4 nanoflowers for cocatalyst-free photocatalytic water splitting

Gancheng Zuo et al.

Summary: Constructing direct Z-scheme heterojunction (DZH) is crucial for improving the efficiency and stability of catalysts for photocatalytic water splitting. In this study, ultrathin TiO2 nanosheets were integrated into ZnIn2S4 to produce TiO2-ZnIn2S4 heterostructure nanoflowers, enhancing the overall system performance. The optimized DZH nanoflowers exhibit enhanced PWS activity and excellent stability, making them promising candidates for efficient water splitting applications.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Review Energy & Fuels

Review on Solar Hydrogen: Its Prospects and Limitations

Suman Dutta

Summary: This review explores various routes for hydrogen generation using solar energy as the primary resource, highlighting the popularity of solar photovoltaic cells combined with water electrolyzers and the potential of biomass conversion for hydrogen production. Economic analysis confirms the viability of hydrogen-fueled cars in terms of both cost-effectiveness and environmental benefits.

ENERGY & FUELS (2021)

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Article Energy & Fuels

Uniformly Dispersed Metal Sulfide Nanodots on g-C3N4 as Bifunctional Catalysts for High-Efficiency Photocatalytic H2 and H2O2 Production under Visible-Light Irradiation

Lei Chen et al.

Summary: Loading transition metal as a cocatalyst onto a photocatalyst is a promising way to enhance photocatalytic reactions. In this study, nickel sulfide nanodots were successfully deposited onto g-C3N4 surface using a light-induced deposition approach, resulting in improved photocatalytic performances for both H-2 evolution and oxygen reduction. The bifunctional catalyst exhibited remarkable activity and stability, attributed to the accurate loading of nickel sulfide nanodots on g-C3N4 nanosheets, boosting charge carrier separation and accelerating chemical reactions on the photocatalyst surface.

ENERGY & FUELS (2021)

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Article Chemistry, Physical

ReS2/ZnIn2S4 heterojunctions with enhanced visible-light-driven hydrogen evolution performance for water splitting

Xin Xiong et al.

Summary: In this study, ReS2/ZnIn2S4 heterojunctions were synthesized for efficient photocatalytic water splitting under visible light irradiation, achieving a significantly enhanced hydrogen evolution rate. The optimized heterostructure exhibited superior photocatalytic performance, with a hydrogen evolution rate about 2.8 times higher than that of pure ZnIn2S4.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Physical

Highly efficient photocatalytic H2 evolution over NiCo2S4/Mn0.5Cd0.5S: Bulk twinned homojunctions and interfacial heterojunctions

Chenxuan Wang et al.

Summary: In this study, a twinned Mn0.5Cd0.5S homojunction and a surface NiCo2S4/T-MCS heterojunction were synthesized and tested for photocatalytic H-2 evolution activity. The combination of these structures was found to enhance charge transfer and separation, significantly improving the hydrogen evolution rate.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Review Materials Science, Multidisciplinary

A review: Synthesis, modification and photocatalytic applications of ZnIn2S4

Jie Wang et al.

Summary: ZnIn2S4, as a promising photocatalytic material, with its wide light absorption range and tunable bandgap, has been widely applied in various fields in recent years. This review introduces the crystal structures, preparation methods, and applications of ZnIn2S4 in photocatalytic systems.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

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Article Chemistry, Multidisciplinary

Direct dual CaIn2S4/Bi2WO6 semiconductor nanocomposites with efficient inter-cross-sectional charge carrier transfer for enhanced visible light photocatalysis

Thillai Sivakumar Natarajan et al.

Summary: Visible light-responsive CaIn2S4 and Bi2WO6 direct dual semiconductor nanocomposites were prepared using hydrothermal and wetness impregnation methods, with enhanced visible light response of Bi2WO6 after coupling with CaIn2S4. The study focused on inter-cross-sectional charge carrier transfer during photocatalysis and improvement in dye adsorption after coupling with CaIn2S4. The synergistic effect of enhanced adsorption capacity and efficient separation of electron-hole pairs contributed to the enhanced photodegradation efficiency under visible light.

JOURNAL OF NANOPARTICLE RESEARCH (2021)

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Article Multidisciplinary Sciences

Interfacial chemical bond and internal electric field modulated Z-scheme Sv-ZnIn2S4/MoSe2 photocatalyst for efficient hydrogen evolution

Xuehua Wang et al.

Summary: The construction of Z-scheme heterostructures is crucial for efficient photocatalytic water splitting. By modulating Mo-S bond and internal electric field, a novel S-v-ZnIn2S4/MoSe2 photocatalyst was developed with high hydrogen evolution rate and apparent quantum yield, demonstrating significant enhancement in photocatalytic performance.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Physical

Assembly of CaIn2S4 on Defect-Rich BiOCl for Acceleration of Interfacial Charge Separation and Photocatalytic Phenol Degradation via S-Scheme Electron Transfer Mechanism

Zhuangzhuang Zhang et al.

Summary: The 2D/2D S-scheme heterostructure of BiOCl nanosheets coupled with CaIn2S4 nanosheet photocatalyst exhibited excellent photocatalytic performance for phenol degradation under visible-light irradiation, attributed to synergistic effects between SOVs, CaIn2S4, and BiOCl in narrowing bandgap and accelerating charge separation. This work provides an efficient method for designing new photocatalysts with SOVs in environmental remediation.

CATALYSTS (2021)

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Article Chemistry, Physical

The in situ construction of ZnIn2S4/CdIn2S4 2D/3D nano hetero-structure for an enhanced visible-light-driven hydrogen production

Xinyu Dang et al.

Summary: ZnIn2S4/CdIn2S4 nano-composites obtained through in situ modification demonstrate excellent photocatalytic activity for hydrogen generation under visible light. The enhanced performance can be attributed to the large number of Cd-S-Zn atomic bridges between ZnIn2S4 nanosheets and CdIn2S4 nano-octahedrons, which promote interfacial charge transfer and inhibit carrier recombination.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Ternary sulfides BaLa2S4 and CaLa2S4 as promising photocatalytic water splitting and thermoelectric materials: First-principles DFT calculations

M. Batouche et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Review Chemistry, Multidisciplinary

Particulate Photocatalysts for Light-Driven Water Splitting: Mechanisms, Challenges, and Design Strategies

Qian Wang et al.

CHEMICAL REVIEWS (2020)

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Article Chemistry, Physical

Aminated flower-like ZnIn2S4 coupled with benzoic acid modified g-C3N4 nanosheets via covalent bonds for ameliorated photocatalytic hydrogen generation

Ziqian Gao et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Chemistry, Physical

Boosting the photocatalytic activity of CdLa2S4 for hydrogen production using Ti3C2 MXene as a co-catalyst

Lin Cheng et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Engineering, Environmental

Construction of CdLa2S4/MIL-88A(Fe) heterojunctions for enhanced photocatalytic H2-evolution activity via a direct Z-scheme electron transfer

Qian Chen et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Multidisciplinary

Rapid Microwave-Assisted Synthesis of CdS/Graphene/MoSx Tunable Heterojunctions and Their Application in Photocatalysis

Iordanis Tzanidis et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Article Energy & Fuels

Rational Design of All-Solid-State 0D/2D Mn0.2Cd0.8S/CeO2 Direct Z-Scheme for Photocatalytic Hydrogen Evolution

Yuanpeng Wang et al.

ENERGY & FUELS (2020)

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Article Chemistry, Inorganic & Nuclear

SiO2@TiO2 Core Shell Nanoparticles Deposited on 2D-Layered ZnIn2S4 to Form a Ternary Heterostructure for Simultaneous Photocatalytic Hydrogen Production and Organic Pollutant Degradation

Lan Wang et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Physical

Broad spectrum response flower spherical-like composites CQDs@CdIn2S4/CdS modified by CQDs with up-conversion property for photocatalytic degradation and water splitting

Jiwei Huang et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Engineering, Environmental

In situ construction efficient visible-light-driven three-dimensional Polypyrrole/Zn3In2S6 nanoflower to systematically explore the photoreduction of Cr(VI): Performance, factors and mechanism

Duidui Wang et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Chemistry, Physical

An Efficient ZnIn2S4@CuInS2 Core-Shell p-n Heterojunction to Boost Visible-Light Photocatalytic Hydrogen Evolution

Xinlei Guo et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

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Article Physics, Applied

A novel S-scheme MoS2/CdIn2S4 flower-like heterojunctions with enhanced photocatalytic degradation and H2 evolution activity

Bin Zhang et al.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2020)

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Article Chemistry, Multidisciplinary

Ultrathin ZnIn2S4 Nanosheets Anchored on Ti3C2TX MXene for Photocatalytic H2 Evolution

Gancheng Zuo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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