4.5 Review

Indigenous Materials as Catalyst Supports for Renewable Diesel Production in Malaysia

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Article Chemistry, Analytical

Hydrodeoxygenation of fatty acid over La-modified HZSM5 for premium quality renewable diesel production

I. Nur Azreena et al.

Summary: In this study, a series of La-HZSM5 catalysts were prepared and investigated for the production of premium quality diesel fuel via hydrodeoxygenation of oleic acid. The La((10))HZSM5((90)) catalyst showed superior activity in producing high quality diesel, attributed to its sufficient weak and medium acid sites as well as mesoporous structure. Vacuum distillation was found to be complementary for producing high quality diesel fractions. The reusability of the La((10))HZSM5((90)) catalyst was also demonstrated.

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Article Thermodynamics

Oil palm empty fruit bunch derived microcrystalline cellulose supported magnetic acid catalyst for esterification reaction: An optimization study

Shamala Gowri Krishnan et al.

Summary: This study demonstrated the successful preparation of high-acidity EFB-MCC/γ-Fe2O3 magnetic acid catalyst with excellent catalytic performance for efficient conversion of oleic acid through esterification reaction. The catalyst exhibited good ferromagnetic properties and mesoporous structure, showing high catalytic efficiency, effective separation, and reusability.

ENERGY CONVERSION AND MANAGEMENT-X (2022)

Review Energy & Fuels

Renewable diesel as fossil fuel substitution in Malaysia: A review

Shir Reen Chia et al.

Summary: Researchers worldwide are searching for sustainable and clean energy sources to reduce environmental impact and ensure continuous energy supply. This review evaluates the potential commercialization of renewable diesel production in Malaysia through comprehensive literature studies. While renewable diesel shows promise as a substitute for fossil fuels, further research is needed to address cost and technological challenges.
Article Energy & Fuels

Catalytic hydrothermal deoxygenation of fatty acids over palladium on activated carbon catalyst (Pd/C) for renewable diesel production

Ifeanyichukwu Edeh et al.

Summary: This study successfully produced high yields of hydrocarbons using palmitic and oleic acids in subcritical water without the addition of hydrogen, with the catalytic effects of 5% palladium on activated carbon. This method has the potential to reduce production costs and increase the capacity to utilize renewable resources for diesel production.

BIOFUELS-UK (2021)

Article Chemistry, Applied

Influential properties of activated carbon on dispersion of nickel phosphides and catalytic performance in hydrodeoxygenation of palm oil

Mustika Ruangudomsakul et al.

Summary: In this study, it was found that the carbon-oxygen ratio of activated carbon derived from wood affects its hydrophobicity, which in turn influences the catalytic performance of nickel phosphide for hydrodeoxygenation of palm oil. The AC derived from Lead tree wood charcoal prepared in Iwasaki kiln showed superior performance compared to that prepared in a tube furnace, with a green diesel yield of 98.3%. The dispersion of Ni2P nanoparticles, as well as the acid properties of the AC, play important roles in the catalytic activity of the system.

CATALYSIS TODAY (2021)

Article Chemistry, Applied

Synthesis of NiMo catalysts supported on Mn-Al2O3 for obtaining green diesel from waste soybean oil

I Vazquez-Garrido et al.

Summary: The addition of 1 mol% manganese to Al2O3 support has been shown to enhance the performance of NiMo catalysts for the hydroconversion of soybean oil, due to the stabilization of manganese oxide species aiding in the redispersion of the active phase.

CATALYSIS TODAY (2021)

Article Agricultural Engineering

Catalytic deoxygenation of waste cooking oil utilizing nickel oxide catalysts over various supports to produce renewable diesel fuel

Wan Nor Adira Wan Khalit et al.

Summary: The research found that Ni-20/AC was the most active catalyst, achieving a hydrocarbon yield of 90% and a selectivity towards n-(C-15 + C-17) of 89% under H-2-free and solvent-free conditions at 350 degrees C and 300 rpm for 3 hours. Additionally, it remained stable over four cycles with consistent hydrocarbon yield (85-87%) and selectivity towards n-(C-15 + C-17) (66-77%). Overall, Ni-20/AC exhibited highly promising catalytic performance due to its good physiochemical properties and high catalyst stability.

BIOMASS & BIOENERGY (2021)

Article Chemistry, Applied

Lipase immobilized graphene oxide biocatalyst assisted enzymatic transesterification of Pongamia pinnata (Karanja) oil and downstream enrichment of biodiesel by solar-driven direct contact membrane distillation followed by ultrafiltration

Ramesh Kumar et al.

Summary: This study successfully demonstrated the production of biodiesel from Karanja seed oil using graphene oxide immobilized lipase biocatalyst and integrated a multi-staged membrane system for efficient separation and recovery of unreacted alcohol and free glycerol. The developed system represents a cost-effective, energy-intensive, and eco-friendly approach for sustainable biofuel production.

FUEL PROCESSING TECHNOLOGY (2021)

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Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni-Mo sulfide catalysts

Thikhamporn Burimsitthigul et al.

Summary: The study investigated the hydrodeoxygenation of palm oil catalyzed by unsupported nickel-molybdenum sulfide, showing that longer reaction time and higher temperature enhanced n-alkane yield. The catalyst with a structure consisting of weakly coupled layers, rim sites, and Ni edges efficiently catalyzed the reaction and could be reused for multiple cycles.

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Synthesis of renewable hydrocarbons from vegetable oil feedstock by hydrotreatment over selective sulfur-free SiO2-Al2O3 supported monometallic Pd, Pt, Ru, Ni, Mo and bimetallic NiMo catalysts

Kristaps Malins

Summary: Screening tests were carried out on various monometallic and bimetallic catalysts synthesized by different impregnation methods to evaluate their performance and selectivity for hydrocarbon production from vegetable oil feedstock with high FFA content. Among them, the Mo-promoted Ni17Mo3DP catalyst exhibited great performance and selectivity, achieving a higher hydrocarbon yield and demonstrating potential for producing renewable hydrocarbons from fatty acid containing raw materials.
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Production of renewable hydrocarbons from vegetable oil refining by-product/waste soapstock over selective sulfur-free high metal loading SiO2-Al2O3 supported Ni catalyst via hydrotreatment

Kristaps Malins

Summary: The study investigated the performance, selectivity, recovery, and reusability of a commercial Ni66 +/- 5%/SiO2-Al2O3 catalyst in renewable hydrocarbon synthesis. By using a solvent-free one-pot hydrotreatment method, combustible gases and high yield linear saturated hydrocarbons were successfully produced from low cost raw material pretreated soapstock, indicating the potential for green energy production.

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Article Green & Sustainable Science & Technology

Transformation of residual fatty raw materials into third generation green diesel over a nickel catalyst supported on mineral palygorskite

Sotiris Lycourghiotis et al.

Summary: The study focused on transforming residual fatty raw materials into third generation green diesel using an active nickel catalyst supported on mineral palygorskite. Biodiesel can be converted into green diesel faster than RFRMs. The composition of the total green diesel is highest in CHO and lowest in SCGO. The catalyst does not affect its main physicochemical characteristics.

RENEWABLE ENERGY (2021)

Review Chemistry, Physical

Recent Progress in Synthesis and Application of Nanosized and Hierarchical Mordenite-A Short Review

Yuri Kalvachev et al.

Summary: Mordenite, a common zeolite, is widely used as an acid catalyst in the petrochemical industry due to its high silica/alumina ratio that allows it to withstand high temperatures and acidic environments. Various modifications, such as crystal size reduction and post-synthetic treatments, are applied to improve diffusion constraints in catalytic processes.

CATALYSTS (2021)

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A promoter effect on hydrodeoxygenation reactions of oleic acid by zeolite beta catalysts

I. Nur Azreena et al.

Summary: This study found that La(10)zeo(90) catalyst exhibited excellent activity and selectivity in the hydrodeoxygenation of oleic acid, mainly attributed to the synergistic interaction between La-Si-Al, abundant weak+ medium acid sites, and excellent textural properties.

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Immobilized Forms of the Ophiostoma piceae Lipase for Green Synthesis of Biodiesel. Comparison with Eversa Transform 2.0 and Cal A

Maria Molina-Gutierrez et al.

Summary: This study analyzed the suitability of a versatile recombinant lipase in the synthesis of biodiesel, with several preparations of immobilized OPEr showing high synthesis yields and potential for commercial production.

JOURNAL OF FUNGI (2021)

Review Energy & Fuels

Recent Development of Renewable Diesel Production Using Bimetallic Catalysts

Shir Reen Chia et al.

Summary: Bimetallic catalysts play a crucial role in the production of renewable diesel by providing unique catalytic properties and enhanced catalytic activities compared to monometallic catalysts. The synergistic interactions in bimetallic catalysts synthesized through various techniques contribute to the enhancement of catalytic activity and could potentially serve as a practical solution in industrial production of renewable diesel.

FRONTIERS IN ENERGY RESEARCH (2021)

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Performance of Activated Carbon Supported Cobalt Oxides and Iron Oxide Catalysts in Catalytic Cracking of Waste Cooking Oil

Tavayogeshwary Thangadurai et al.

Summary: This study investigated the catalyst activity of activated carbon supported Co, Fe, and Co-Fe oxides in catalytic cracking of waste cooking oil. The results showed that the bimetal Co-Fe/AC catalysts had a synergistic effect, leading to an increase in liquid hydrocarbon yield and fatty acid conversion.

PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING (2021)

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Synthesis of the SrO-CaO-Al2O3 trimetallic oxide catalyst for transesterification to produce biodiesel

Yujiao Zhang et al.

Summary: The composite catalyst 0.4-SrO-CaO-Al2O3 shows the best catalytic capability in transesterification of palm oil with methanol to produc biodiesel, achieving a FAME yield of 98.16%. The stability and reusability of the catalyst are greatly enhanced by reducing leaching out of active species. The modification method for SrO-CaO-Al2O3 is feasible for enhancing catalytic stability in transesterification.

RENEWABLE ENERGY (2021)

Article Chemistry, Applied

W promoted Ni-Al2O3 co-precipitated catalysts for green diesel production

Christos Papadopoulos et al.

Summary: In this study, the promoting action of tungsten (W) in Ni-Al2O3 co-precipitated catalysts with high nickel loading was investigated. It was found that a WNi-Al2O3 catalyst containing 8 wt% W and 35 wt% Ni showed the highest efficiency, attributed to various factors such as increasing specific surface area, regulating acidity, decreasing inactive nickel-aluminate formation, and the participation of W5+-oxo species. The optimal reduction-activation temperature was identified to be 500°C, balancing various factors for improved performance.

FUEL PROCESSING TECHNOLOGY (2021)

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Biodiesel Upgrading to Renewable Diesel over Nickel Supported on Natural Mordenite Catalysts

Konstantina Fani et al.

Summary: In this study, natural mordenite was activated by acid treatment to serve as a catalyst support for Ni catalysts. The catalysts synthesized using the deposition-precipitation method showed the highest efficiency in biodiesel upgrading, with almost complete conversion and production of the highest amount of green diesel. This was attributed to enhanced specific surface area, better nickel dispersion, and reduced carbon deposits on the catalyst surface.

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Cobalt-Alumina Coprecipitated Catalysts for Green Diesel Production

Ioannis Nikolopoulos et al.

Summary: Cobalt-alumina catalysts with high cobalt loading were synthesized, and the most efficient catalyst for green diesel production was found to contain 55 wt% cobalt activated at 500 degrees C. The catalysts exhibited lower performance in the deoxygenation of waste cooking oil compared to sunflower oil, likely due to deactivation caused by coking and pore blockage.

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Catalytic deoxygenation by H2-free single-step conversion of free fatty acid feedstock over a Co-Ag carbon-based catalyst for green diesel production

M. Safa-Gamal et al.

Summary: Activated carbon-supported Co-Ag catalysts showed high deoxygenation efficiency and conversion of fatty acids to hydrocarbon liquid products, with a synergistic effect between the active metals and activated carbon support significantly facilitating the selective deoxygenation pathway.

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Article Chemistry, Physical

A study of the mechanism of triglyceride hydrodeoxygenation over alumina-supported and phosphatized-alumina-supported Pd catalysts

Anna Vikar et al.

Summary: The study investigated the mechanism of catalytic hydrodeoxygenation of fats, vegetable oils, and fatty acids, finding that surface modification of the support alumina with phosphate groups significantly increased the activity of the Pd catalyst and improved paraffin yield. The research also indicated that carboxylates of less basic surface sites were more prone to HDO reaction than those of strong base sites, highlighting the importance of surface properties in the reaction process.

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Development of a green integrated process for biodiesel esters production: Use of fermented macauba cake as biocatalyst for macauba acid oil transesterification

Sabrini N. S. Avila et al.

Summary: A new green integrated process for biodiesel ester production was developed, using low-cost biocatalysts and a low-value oil for enzymatic transesterification. This method can reduce production costs and optimize raw material utilization.

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Mohammed Salaheldeen et al.

Summary: Triglycerides, derived from natural sources such as virgin vegetable oils and animal fats, are the main components used for biodiesel production. Biodiesel, considered an attractive alternative fuel to diesel with environmental advantages, is typically produced through transesterification. Commercialization of biodiesel is limited by high production costs, with the transesterification route being a crucial factor. Various modifications to the conventional method and innovative technologies have been proposed to improve biodiesel production efficiency and lower costs.

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Suppasate Dechakhumwat et al.

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