4.7 Review

Recent advances in the synthesis of and sensing applications for metal-organic framework-molecularly imprinted polymer (MOF-MIP) composites

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Recent advances in process engineering and upcoming applications of metal-organic frameworks

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Summary: Progress in metal-organic frameworks (MOFs) has advanced to commercialization, but the diversity of individual goals has led to a variety of research approaches. This review examines the issues, demands, and recent advances in MOF commercialization, including criteria such as stability, producibility, regulations, and production cost.

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Hollow porous molecularly imprinted polymers as emerging adsorbents*

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Yichuan Cao et al.

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Ultrasensitive and selective molecularly imprinted electrochemical oxaliplatin sensor based on a novel nitrogen-doped carbon nanotubes/Ag@cu MOF as a signal enhancer and reporter nanohybrid

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Summary: A method for electrochemical trace detection of NOR was developed using Ppy-based MIP-coated 3D CoFe-MOFs with AuNPs. After modification, CoFe-MOFs/AuNPs generated more imprinted cavities, contributing to a lower detection limit of 0.131 pmol L-1 and a wider linear range. Rapid and precise detection of NOR was achieved in prescription and pure milk, showing high potential for trace detection in environmental and animal foods.

ELECTROCHIMICA ACTA (2021)

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Molecularly imprinted polymers based on magnetically fluorescent metal-organic frameworks for the selective detection of hepatitis A virus

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Thermo-responsive imprinted hydrogel with switchable sialic acid recognition for selective cancer cell isolation from blood

Yue Ma et al.

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Ultrasensitive electrochemical molecularly imprinted sensor based on AuE/Ag-MOF@MC for determination of hemoglobin using response surface methodology

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Summary: A highly sensitive electrochemical sensor was developed for determining hemoglobin levels, utilizing an AuE modified with Ag-MOF@MC and MIPs to create a sensing system. The system showed a wide linear dynamic range and low detection limit for Hb concentration measurement, with good stability and reproducibility. The sensor was successfully applied to real blood samples, demonstrating acceptable recovery and reliability in Hb determination.

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Novel SeS2-loaded Co MOF with Au@PANI comprised electroanalytical molecularly imprinted polymer-based disposable sensor for patulin mycotoxin

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Summary: A sensor for detecting PT molecules was developed using electropolymerized molecularly imprinted polymer as the base matrix of the electrode, achieving higher sensitivity and stability.

BIOSENSORS & BIOELECTRONICS (2021)

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Isoreticular chemistry within metal-organic frameworks for gas storage and separation

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Design of turn-on luminescent sensor based on nanostructured molecularly imprinted polymer-coated zirconium metal-organic framework for selective detection of chloramphenicol residues in milk and honey

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Enhanced molecular imprinted electrochemical sensing of histamine based on signal reporting nanohybrid

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