期刊
COORDINATION CHEMISTRY REVIEWS
卷 458, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2022.214421
关键词
Manganese complexes; Bidentate ligands; Hydrogenation; Transfer Hydrogenation; Hydrogen borrowing; Hydrosilylation
资金
- Centre National de la Recherche Scientifique (CNRS)
- Russian Science Foundation [20-73-00311]
- Universite Toulouse III Paul Sabatier
- Institut Universi-taire de France (IUF)
- Embassy of Yemen in Paris
- program Pause
- French Embassy in Moscow
- Russian Science Foundation [20-73-00311] Funding Source: Russian Science Foundation
This paper provides a comprehensive review of the rapidly emerging application of organometallic manganese complexes in catalytic reactions. It focuses on the influence of different donor ligands on catalytic activity and selectivity, the comparison with polydentate systems, and the study of mechanistic aspects.
Rapidly emerging application of organometallic manganese complexes incorporating less elaborated mono- and bidentate donor ligands in catalytic hydrogenation, transfer hydrogenation, hydrogenborrowing and hydrosilylation processes is comprehensively reviewed. Special attention is devoted to the influence of the nature of donor moieties (P-, N- and C-donors) on the catalytic activity and/or selectivity, the comparison with structurally related polydentate systems and mechanistic aspects.CO 2022 Elsevier B.V. All rights reserved.
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