Metal-organic and covalent organic frameworks for the remediation of aqueous dye solutions: Adsorptive, catalytic and extractive processes

Environmental pollution caused by various industries has contributed to water contamination which threatens human life worldwide. Thus, investigation of affordable and efficient technologies to deal with the challenge of water purification is critical. Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) with tunable backbones and functionalities offer excellent opportunities in the field of water remediation. In this review, we describe the targeted design of MOFs and COFs as well as some key issues related to tuning the structures and boosting the stability of these materials for adsorptive, catalytic and extractive removal of organic dyes in water. Furthermore, we provide an overview of the reported approaches in this field and present strategies for selective removal of the pollutants by taking the advantage of the framework features of MOFs and COFs. In addition, the regeneration of these networks after the removal process and their advantages over conventional catalysts for cleaning water are represented. Finally, we expect the current review gives some insight into tailoring the structure of MOFs and COFs for water remediation. (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

Environmental pollution caused by various industries has led to water contamination, posing a threat to human life worldwide. Therefore, it is crucial to explore affordable and efficient technologies for water purification. Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) offer great potential in the field of water remediation. This review discusses the targeted design of MOFs and COFs, as well as key issues related to adjusting their structures and enhancing their stability for the removal of organic dyes through adsorption, catalysis, and extraction in water.