期刊
COMPOSITES SCIENCE AND TECHNOLOGY
卷 220, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compscitech.2022.109302
关键词
A. Multifunctional composites; B. Electrical properties; B. Thermal properties; D. Transmission electron microscopy (TEM)
资金
- National Natural Science Foundation of China [51876112]
- Shanghai Sailing Program [21YF1414200]
- Discipline of Shanghai-Materials Science and Engineering
- Shanghai Engineering Research Center of Advanced Thermal Functional Materials
In this study, a novel fluorinated graphene aerogel/polydimethylsiloxane composite material with high compressibility and superior thermal conductivity was successfully fabricated. This composite material exhibited excellent insulation properties with ultra-low electrical conductivity and demonstrated outstanding heat dissipation performance as a thermal interface material. Furthermore, it also showed excellent flame retardant properties.
Although graphene-based composites have been considered desirable candidates for thermal management applications, their poor electrical insulation restricts their further use in electrical insulation requiring occasions. Fluorinated graphene (FG), a new type of graphene-based material, attracts the attention of researchers due to its excellent electric insulation property. In this work, a novel fluorinated graphene aerogel/polydimethylsiloxane (FGA/PDMS) composite with a tightly-packed structure is constructed via freeze-drying and vacuum impregnation. The fabricated composite shows high compressibility and superior thermal conductivity of 1.41 W/(m.K) with a relatively low FGA loading of 0.28 wt%, 605.6% larger than the original PDMS. Meanwhile, it also maintains excellent insulation properties with an ultra-low electrical conductivity of 2.0 x 10(-9) S/(cm). 180 times smaller than graphene aerogel/PDMS. The practical excellent heat dissipation performance of the composite functioning as thermal interface material is also verified by a thorough study theoretically and experimentally. Furthermore, the FGA/PDMS composite also behaves with excellent flame retardant properties.
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