期刊
CHEMSUSCHEM
卷 15, 期 13, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202200228
关键词
5-hydroxymethylfurfural; biomass valorization; homogeneous catalysis; ligands; sustainable chemistry
资金
- Universita degli Studi di Bologna within the CRUI-CARE Agreement
This review discusses recent developments in homogeneous catalysts for the transformation of HMF, including the effects of metal nature, ligands, solvents, and reaction conditions. Current issues and future opportunities are also presented.
5-Hydroxymethylfufural (HMF) is an intriguing platform molecule that can be obtained from biomasses and that can lead to the production of a wide range of products, intermediates, or monomers. The presence of different moieties in HMF (hydroxy, aldehyde, furan ring) allows to carry out different transformations such as selective oxidations and hydrogenations, reductive aminations, etherifications, decarbonylations, and acetalizations. This is a great chance in a biorefinery perspective but requires the development of active and highly selective catalysts. In this view, homogeneous catalysis can lead to efficient conversion of HMF at mild reaction conditions. This Review discussed the recent achievements in homogeneous catalysts development and application to HMF transformations. The effects of metal nature, ligands, solvents, and reaction conditions were reported and critically reviewed. Current issues and future chances have been presented to drive future studies toward more efficient and scalable processes.
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