Distribution and ecological risk assessment of heavy metals using geochemical normalization factors in the aquatic sediments

Thamirabharani river acquires a noticeable quantity of sewage and agriculture waste from local inhabitants. The distribution of heavy metals in the surface sediments of the Thamirabharani river was analyzed using Inductively Coupled Plasma- Mass Spectrometry (ICP-MS) to study the ecological risks. The heavy metal concentrations in the sediments ranged from 0.098 +/- 0.03(Cd) to 159.181 +/- 13.36 mg kgxe213; 1 (Fe). The Cd, Zn, Ni, Fe, and Mn concentrations in the sediments were above the US Environmental Protection Agency-Sediment Quality Guidelines. The fact that Cd, Co, and Cu concentrations at sites 4 and 5 exceeded the background values (BGVs) of 0.2, 13, and 32 mg kgxe213; 1 suggests anthropogenic activity, notably in the downstream of the river. The sediment contaminated with Cd is more evident, particularly in the estuarine region. The potential ecological risk index (150<= 300) and ecological risk co-efficient (40 < Er < 80) revealed moderate ecological risk at the estuarine region (S5). There was a moderate level of pollution in the downstream region (S4 and S5) based on a geo-accumulation index (Igeo), contamination factor (CF), pollution load index (PLI), and the moderate degree of contamination (mCd) values. According to the geochemical normalization factors, the downstream region (sites 4 and 5) was moderately polluted than the upstream region (S1 and S2), which may affect the estuarine/marine ecosystem. This information may facilitate the relevant regulatory authorities to implement the requisite stringent monitoring program in the aquatic ecosystem.

Automated summary

The Thamirabharani river is contaminated with high concentrations of heavy metals, especially in the estuarine region. This poses a moderate ecological risk to the marine ecosystem. Therefore, stringent monitoring measures need to be implemented by the relevant regulatory authorities.