Simply synthesized sodium alginate/zirconium hydrogel as adsorbent for phosphate adsorption from aqueous solution: Performance and mechanisms

The traditional zirconium hydrogel beads were synthesized by multi-step method, which was comparatively complex. In this study, a high phosphate removal efficient sodium alginate/zirconium (SA/Zr) hydrogel was synthesized by a simple method, with the phosphate adsorption performance and mechanism be explored. The results showed that the adsorption capacity of SA/Zr hydrogel to phosphate was greatly affected by pH. With the increase of initial pH (3-11), the adsorption capacity of SA/Zr for phosphate descended. The phosphate adsorption capacity of SA/Zr hydrogel exceeded 120 mg PO43-/g at pH 2-7, while reaching the maximum adsorption capacity at pH 3 (256.79 mg PO43-/g). The process of adsorption kinetics was well fitted by intraparticle diffusion model, indicating that there was chemical adsorption during the adsorption process. The Redlich-Peterson isotherm model can well accord with isotherm data. In addition, the material showed high selectivity to phosphate. Besides, combining X-ray photoelectron spectroscopy with Zeta potential results suggested that when the pH value was less than 4.19, SA/Zr hydrogel adsorbed phosphate by electrostatic attraction and hydrogen bonding while the adsorption was made mainly through ligand exchange when pH value was higher than 4.19.

Automated summary

A high phosphate removal efficient SA/Zr hydrogel was synthesized by a simple method and its adsorption performance and mechanism were investigated. The results showed that pH significantly influenced the adsorption capacity of the hydrogel for phosphate, with high selectivity. The findings have important implications for water treatment and phosphate pollution control.