Incorporation of SiO2 functionalized gC3N4 sheets with TiO2 nanoparticles to enhance the anticorrosion performance of metal specimens in aggressive Cl- environment

Nowadays, carbon-based nano-structured materials are widely preferred for composite coating as anti-corrosive reinforcement mainly due to its enhanced physical, chemical and mechanical properties. Herein we develop highly efficient Graphitic carbon nitride-Silica-Titania (gC(3)N(4)/SiO2/TiO2) ternary nanocomposite are synthesized and it is used as a nanofillers in the corrosive protection layer on the proposed metal specimen (i.e., mild steel specimen) in an aggressive chloride environment. Size, structural and morphological analysis were analysed for the confirmation of presence of particles. gC(3)N(4) is currently earning quite drastic attention, owing to its affordable cost compared to carbon nanotubes and other carbon-based materials, when gC(3)N(4) incorporated with SiO2 and TiO2, the composite matrix greatly improves the mechanical strength of the coating mixture. XRD, XPS, EDS analysis projects excellent formation and presence of the ternary nanocomposites. The particles are well dispersed in epoxy and organic resin and deposited on the mildsteel panels and it is examined using various surface and structural characterization techniques. The obtained results are very encouraging and the ternary composite coatings can be recommended for real world applications.

Automated summary

Carbon-based nano-structured materials are widely used in composite coating for anti-corrosive reinforcement. The highly efficient gC(3)N(4)/SiO2/TiO2 ternary nanocomposite enhances the physical, chemical and mechanical properties of the coating, making it suitable for real-world applications.