4.7 Review

Comprehensive review on advanced reusability of g-C3N4 based photocatalysts for the removal of organic pollutants

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Article Engineering, Environmental

Construction of Fe3O4@β-CD/g-C3N4 nanocomposite catalyst for degradation of PCBs in wastewater through photodegradation and heterogeneous Fenton oxidation

Hui Wang et al.

Summary: A multifunctional magnetic beta-cyclodextrin/graphitic carbon nitride catalyst (Fe3O4@beta-CD/g-C3N4) was fabricated for PCBs degradation, exhibiting superior catalytic activity and the ability to be reused multiple times without significant deterioration. The catalyst showed a super synergy of photodegradation and heterogeneous Fenton oxidation, leading to efficient degradation of PCBs in both river water and municipal wastewater, showcasing great potential for environmental remediation.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

Preparation of floating porous g-C3N4 photocatalyst via a facile one-pot method for efficient photocatalytic elimination of tetracycline under visible light irradiation

Jialin Tang et al.

Summary: The floating porous g-C3N4 (FPCN) synthesized via a one-pot method shows excellent photocatalytic performance, outperforming traditional powder catalysts in terms of efficiency in removing tetracycline. The 3D interconnected network and enhanced light absorption of FPCN contribute to its superior performance, offering a promising solution to the recycling issue of powder catalysts.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

Fast and lasting electron transfer between γ-FeOOH and g-C3N4/kaolinite containing N vacancies for enhanced visible-light-assisted peroxymonosulfate activation

Xiangwei Zhang et al.

Summary: The novel ternary composite FNGK showed superior degradation efficiency of BPA in the presence of PMS under visible-light irradiation, with accelerated PMS consumption and enhanced electron transfer efficiency due to the introduction of kaolinite. The trapping of photo-generated carriers by N vacancies and gamma-FeOOH improved the separation potency of charge carriers and reduction efficiency of Fe(III) to Fe(II), demonstrating a new perspective for efficiently degrading organic contaminants through the coupling application of PMS activation and photocatalytic technology.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

Facile fabrication of TaON/Bi2MoO6 core-shell S-scheme heterojunction nanofibers for boosting visible-light catalytic levofloxacin degradation and Cr(VI) reduction

Shijie Li et al.

Summary: The study developed a novel TaON/Bi2MoO6 S-scheme heterojunction photocatalyst with a core-shell fiber-shaped structure, demonstrating high catalytic activity towards levofloxacin antibiotic degradation and Cr(VI) reduction. The material showed excellent stability and reusability, and a possible photocatalytic reaction mechanism for removal of LEV and Cr(VI) was proposed, providing insights for fabricating efficient water purification photocatalysts.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Designing of TiO2/α-Fe2O3 coupled g-C3N4 magnetic heterostructure composite for efficient Z-scheme photo-degradation process under visible light exposures

Renji Rajendran et al.

Summary: A novel ternary magnetic nanocomposite composed of g-C3N4, TiO2, and alpha-Fe2O3 was successfully fabricated, demonstrating a high photocatalytic degradation efficiency of 95.7% for Rhodamine B under visible-light exposure. This efficient degradation is attributed to the synergistic interface among the three components in the nanocomposite, leading to effective electron/hole separation, enhanced redox species, and excellent visible-light utilization. Additionally, the magnetic nanocomposite showed great durability with a consistent high degradation rate for Rhodamine B after five consecutive cycles, making it a promising candidate for wastewater treatment.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

Core-shell P-laden biochar/ZnO/g-C3N4 composite for enhanced photocatalytic degradation of atrazine and improved P slow-release performance

Xiongfang An et al.

Summary: The newly developed Pbi-ZnO-g-C3N4 composite can efficiently degrade atrazine and improve phosphorus utilization efficiency, showing significant slow-release performance.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Engineering, Environmental

Effect of carbon nitride synthesized by different modification strategies on the performance of carbon nitride/PVDF photocatalytic composite membranes

Boru Gao et al.

Summary: In this study, different modified carbon nitride (CN) were incorporated into polyvinylidene fluoride (PVDF) to form a photocatalytic composite membrane (PCM). The PCM showed improved permeability, anti-fouling characteristic, and photocatalytic self-cleaning activity, with DCN/PVDF exhibiting the highest porosity and hydrophilicity. Additionally, the modified CN/PVDF exhibited excellent photocatalytic activity for the removal of cefotaxime (CFX) and E. coli, with DCN30/PVDF achieving high removal rates within a short period of time.

JOURNAL OF HAZARDOUS MATERIALS (2022)

Article Engineering, Environmental

Magnetic 2D/2D oxygen doped g-C3N4/biochar composite to activate peroxymonosulfate for degradation of emerging organic pollutants

Shizong Wang et al.

Summary: A magnetic 2D/2D oxygen-doped graphite carbon nitride/biochar composite was fabricated and used to activate peroxymonosulfate for the degradation of emerging organic pollutants. The composite showed superior catalytic activity, complete degrading antibiotic SMX and other emerging organic pollutants, with good photocatalytic activity under visible light. This enhanced catalytic activity was attributed to improved interfacial charge transfer and adsorption capacity.

JOURNAL OF HAZARDOUS MATERIALS (2022)

Article Chemistry, Physical

Photocatalytic degradation of Rhodamine B over TiO2/g-C3N4 and immobilized TiO2/g-C3N4 on stainless steel wire gauze under UV and visible light: A detailed kinetic analysis and mechanism of degradation

N. Premalatha et al.

Summary: An efficient visible light-driven TiO2 anchored on g-C3N4 composite was synthesized using a one-step hydrothermal method. Characterization and performance studies were conducted, revealing its excellent photocatalytic degradation capability. The influence of different conditions on RhB degradation was investigated, and a possible degradation mechanism was proposed. The performance of wire gauze coated TiO2/g-C3N4 composite was compared with TiO2/g-C3N4 nanoparticles, demonstrating enhanced photocatalytic activity.

REACTION KINETICS MECHANISMS AND CATALYSIS (2022)

Article Engineering, Environmental

Strongly coupled cobalt/oxygen co-doped porous g-C3N4 heterostructure with abundant oxygen vacancies modulated the peroxymonosulfate activation pathway

Jian Ye et al.

Summary: The highly dispersed Co-O@CN-150 heterostructure was successfully fabricated, which not only regulated the PMS activation pathway and provided more active sites, but also achieved complete degradation of ofloxacin within 20 minutes and self-cleaning performance.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

High-efficiency, compressible, and recyclable reduced graphene oxide/chitosan composite aerogels supported g-C3N4/BiOBr photocatalyst for adsorption and degradation of rhodamine B

Hongyang Pan et al.

Summary: Photocatalytic technology is a highly efficient and promising sewage treatment technology. However, its recycling difficulty limits its applications. In this research, a composite aerogel with excellent properties was developed for the adsorption and degradation of RhB dye. The composite showed good adsorption and degradation performance, as well as recycling and mechanical properties.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

Article Engineering, Environmental

Fabrication of visible-light-driven tubular F, P-codoped graphitic carbon nitride for enhanced photocatalytic degradation of tetracycline

Manh Dung Nguyen et al.

Summary: The tubular g-C3N4 photocatalyst doped with fluorine and phosphorus has shown improved photocatalytic degradation efficiency of tetracycline. The structural design enhances electrical conductivity and electron transfer rate, while the addition of fluorine atoms effectively decreases the bandgap and recombination rate, leading to enhanced photocatalytic degradation effects.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

Review Materials Science, Multidisciplinary

A review of the current status of graphitic carbon nitride

Nicholas Rono et al.

Summary: Graphitic carbon nitride (g-C3N4) is a significant material with attractive optoelectronic properties, but requires modification for improved performance. This review evaluates the synthesis, modifications, and applications of g-C3N4, emphasizing the use of theoretical strategies to understand its properties.

CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES (2021)

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Recent developments of doped g-C3N4 photocatalysts for the degradation of organic pollutants

Xiaolu Liu et al.

Summary: Graphitic carbon nitride (g-C3N4) has high thermal stability and a moderate band gap, but its performance is limited by issues like insufficient absorption of visible light. Element doping is an effective strategy to enhance its photocatalytic properties and improve performance.

CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2021)

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In situ growth of boron doped g-C3N4 on carbon fiber cloth as a recycled flexible film-photocatalyst

Lin Lei et al.

Summary: This study developed a boron-doped graphitic carbon nitride (BCN) film photocatalysts on carbon fiber cloth with improved mechanical stability and recyclability. The porous structure, boron doping, and carbon fiber cloth support enhanced light capture, charge separation and transport, as well as dye adsorption capabilities.

CERAMICS INTERNATIONAL (2021)

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Improved anti-biofouling performance of CdS/g-C3N4/rGO modified membranes based on in situ visible light photocatalysis in anammox membrane bioreactor

Lingfeng Ni et al.

Summary: The CdS/g-C3N4/rGO photocatalyst enhances membrane hydrophilicity and water permeability, inhibits foulant and bacteria attachment, prolongs membrane lifespan, and reduces clogging, showing potential for improving total nitrogen removal efficiency in anammox MBRs.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Chemistry, Physical

Engineering carbon-defects on ultrathin g-C3N4 allows one-pot output and dramatically boosts photoredox catalytic activity

Shuying Gao et al.

Summary: By integrating carbon-defect engineering and 2-dimensional engineering, an ultrathin g-C3N4 photocatalyst with superior structural properties and enhanced reduction ability was successfully synthesized, leading to increased hydrogen production and efficient degradation of organic pollutants. The prominent features of the catalyst include a porous structure with abundant carbon defects and improved hydrophilicity.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Organic dye-reformed construction of porous-defect g-C3N4 nanosheet for improved visible-light-driven photocatalytic activity

Peng Song et al.

Summary: A novel strategy of synthesizing high-active g-C3N4 through organic dye-reformed melamine precursor has been developed, showing enhanced visible-light-driven photocatalytic degradation activity towards Rhodamine B dye. This approach opens up a new pathway for the development of efficient, economic and environmental-friendly photocatalysts.

APPLIED SURFACE SCIENCE (2021)

Article Engineering, Environmental

Porous self-floating 3D Ag2O/g-C3N4 hydrogel and photocatalytic inactivation of Microcystis aeruginosa under visible light

Gongduan Fan et al.

Summary: This study successfully synthesized self-floating Ag2O/g-C3N4/hydrogel photocatalytic composites with a porous three-dimensional nanostructure, which showed good removal efficiency of Microcystis aeruginosa under visible light irradiation. Various factors influencing the performance of the photocatalyst were investigated, highlighting the potential practical applications in tackling harmful algal blooms in natural water bodies.

CHEMICAL ENGINEERING JOURNAL (2021)

Review Engineering, Environmental

A critical review of g-C3N4-based photocatalytic membrane for water purification

Menglu Zhang et al.

Summary: Photocatalytic membranes offer an energy sustainable and eco-friendly approach for water purification with enhanced efficiency and self-cleaning performance. Utilizing graphite carbon nitride to construct membranes with visible-light responsiveness is of great scientific significance for long-term stability and solar energy utilization.

CHEMICAL ENGINEERING JOURNAL (2021)

Review Chemistry, Applied

Applications of chitin and chitosan based biomaterials for the adsorptive removal of textile dyes from water-A comprehensive review

Palliyalil Sirajudheen et al.

Summary: The study discusses the importance of developing new technologies for wastewater treatment and recycling of dye contaminated water, with a focus on using surface modified chitin and chitosan biopolymeric composites as adsorbents to enhance dye removal efficiency. The research emphasizes the versatility of composites for rapid, selective, and effective removal processes for the detoxification of a variety of organic dyes via adsorption techniques.

CARBOHYDRATE POLYMERS (2021)

Review Engineering, Environmental

Synthesis strategies and emerging mechanisms of metal-organic frameworks for sulfate radical-based advanced oxidation process: A review

Zhaokun Xiong et al.

Summary: This article provides an in-depth overview of the state-of-the-art metal-organic frameworks (MOFs)-based materials for sulfate radical-based advanced oxidation processes (SR-AOPs) applications, summarizing synthetic strategies, applications in wastewater treatment, and theoretical calculations to predict reaction mechanisms. Special emphasis is placed on the effects of structure on catalytic activities and the circumstances of radical and non-radical reaction mechanisms in MOFs-based SR-AOPs. Future research directions and unresolved challenges are also discussed.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Engineering, Environmental

Nitrogen defect engineering and π-conjugation structure decorated g-C3N4 with highly enhanced visible-light photocatalytic hydrogen evolution and mechanism insight

Yingying Qin et al.

Summary: The study demonstrates the potential of utilizing a precise molecular tunability strategy to enhance the photocatalytic performance of metal-free photocatalysts for hydrogen evolution. By integrating N defect engineering and pi-conjugation structure into g-C3N4, the photocatalytic hydrogen evolution rate was significantly increased, providing insights on the role of structural defects in improving photocatalytic activity.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Physical

Graphitic-C3N4 coated floating glass beads for photocatalytic destruction of synthetic and natural organic compounds in water under UV light

Jianing Hui et al.

Summary: This study introduces a facile method to coat g-C3N4 onto porous glass beads, producing a highly efficient photocatalyst for the removal of organic pollutants and cyanobacterial toxins in water reservoirs. Through recycling experiments, the coated layer is proven to be highly stable and regenerative.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2021)

Article Environmental Sciences

Immobilization of visible-light-driven photocatalyst g-C3N4 on ceramic fiber for degradation of organic dye

Jeonghyun Hong et al.

Summary: This study explores the use of a three dimensional based-ceramic fiber as a substrate and graphitic carbon nitride (g-C3N4) as a visible-light-driven photocatalyst in wastewater treatment. The immobilization of g-C3N4 on ceramic fiber using a co-calcination method and its photodegradation activity under visible light were examined for their potential application in practical wastewater treatment.

TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY (2021)

Article Chemistry, Physical

In-situ construction of metallic Ni3C@Ni core-shell cocatalysts over g-C3N4 nanosheets for shell-thickness-dependent photocatalytic H2 production

Rongchen Shen et al.

Summary: The shell-thickness-controlled Ni3C@Ni/g-C3N4 photocatalysts were designed with intimate Schottky junctions using an in situ high-temperature transformation strategy. Optimized Ni shell-layer thickness of 15 nm achieved the best visible-light photocatalytic H2-production performance. The intimate Schottky-junctions hinder rapid charge recombination, increase reactive sites, and boost catalytic kinetics, leading to shellthickness-dependent hydrogen evolution.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Applied

Enhancement of Cr(VI) removal efficiency via adsorption/photocatalysis synergy using electrospun chitosan/g-C3N4/TiO2 nanofibers

Qing-Hao Li et al.

Summary: Chitosan/g-C3N4/TiO2 (CS/CNT) nanofibers were fabricated for Cr(VI) removal using adsorption and photocatalytic processes. The addition of g-C3N4/TiO2 enhanced the acid resistance of CS, leading to improved removal efficiency of Cr(VI) under visible-light irradiation through synergistic effect of adsorption and photocatalysis.

CARBOHYDRATE POLYMERS (2021)

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Recent advances in anion doped g-C3N4 photocatalysts: A review

Sulagna Patnaik et al.

Summary: The rapid industrialization and globalization today have led to sustainable development of diversity, with photocatalytic nano-materials emerging to combat environmental pollution and energy crisis. Various modifications of g-C3N4 have been introduced to broaden its potential applications, with band gap engineering through elemental doping considered as a successful approach to modify its optical and electronic properties.

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A novel PVDF-TiO2@g-C3N4 composite electrospun fiber for efficient photocatalytic degradation of tetracycline under visible light irradiation

Xiarong Zheng et al.

Summary: A novel composite electrospun fiber with high photocatalytic efficiency and stability was synthesized, suitable for degrading pollutants in water bodies, with a rough surface and extreme hydrophilicity to enhance catalyst adhesion.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2021)

Article Environmental Sciences

Photocatalytic degradation of 2,4-dicholorophenoxyacetic acid by TiO2 modified catalyst: kinetics and operating cost analysis

Akash Balakrishnan et al.

Summary: A recirculation type photocatalytic reactor using chitosan-TiO2 beads was developed to effectively treat 2,4-dichlorophenoxyacetic acid in water bodies, showing a higher photocatalytic degradation efficiency compared to commercial TiO2. The study highlights the reliability, low cost, efficiency, reusability, and potential commercialization of the photocatalytic removal technology.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

Article Chemistry, Physical

Synergistic interaction of Z-scheme 2D/3D g-C3N4/BiOI heterojunction and porous PVDF membrane for greatly improving the photodegradation efficiency of tetracycline

Yanhua Cui et al.

Summary: This study successfully designed photocatalytic membranes with exceptional photocatalytic degradation efficiency and self-cleaning ability by blending Z-scheme 2D/3D g-C3N4/BiOI heterojunction with beta-phase PVDF membrane matrix. The membranes showed remarkable permeability, stability, and reusability, as well as enhanced photoinduced carrier separation efficiency, opening up a novel strategy for high-efficient photocatalytic membranes in water treatment applications.

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Article Chemistry, Physical

Highly synergic adsorption/photocatalytic efficiency of Alginate/Bentonite impregnated TiO2 beads for wastewater treatment

Soulaima Chkirida et al.

Summary: Green approaches have become a trend for solving aquatic environmental issues by satisfying the triple lines of sustainability. A new eco-friendly adsorbent with combined adsorption and photocatalytic properties was successfully designed and showed positive impact in the challenging wastewater sector. The morphology, pH-sensitive swelling behavior, and photocatalytic efficiency of the prepared beads were emphasized and validated through the removal of methylene blue from aqueous solutions.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2021)

Article Chemistry, Physical

A novel layer-layer crossed structure of bentonite/g-C3N4 for enhanced photocatalytic oxidation of arsenic(III) in a wide pH range

Chunli Wang et al.

Summary: A novel 2D-2D bentonite/g-C3N4 composite with a layer-layer cross structure and large surface area was successfully synthesized for the photocatalytic oxidation of arsenic in wastewater. The composite exhibited a significantly higher As(III) oxidation rate compared to pure g-C3N4, attributed to the enhanced specific surface area and suppressed electron-hole recombination. Additionally, the composite showed high photocatalytic oxidation efficiency over a wide pH range.

SURFACES AND INTERFACES (2021)

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Recent progress in g-C3N4, TiO2 and ZnO based photocatalysts for dye degradation: Strategies to improve photocatalytic activity

Meena Nemiwal et al.

Summary: The review discusses the issue of water contamination by dyes and explores the potential solution using semiconductor-assisted materials and renewable solar energy. By developing semiconductor composite and heterojunction systems, the efficiency and stability of photocatalysts have been enhanced.

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Article Green & Sustainable Science & Technology

A reusable, separation-free and biodegradable calcium alginate/g-C3N4 microsphere for sustainable photocatalytic wastewater treatment

Derek Hao et al.

Summary: The study demonstrates a facile preparation method of g-C3N4 hydrogel microspheres with high photocatalytic activity for organic pollutant control, by utilizing cross-link reactions between sodium alginate and calcium ions. The hydrogel microspheres show good cycle stability and can be reused for multiple cycles, while also being biodegradable for methane production, offering new inspiration for the development of easily reusable and sustainable photocatalysts for wastewater treatment.

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Preparation of the additive-modified α-Fe2O3/g-C3N4 Z-scheme composites with improved visible-light photocatalytic activity

Derong Sun et al.

Summary: A hollow alpha-Fe2O3 (S3) sample with high-activity was successfully obtained by adding H2PO4- and Cu2+ ions via a hydrothermal process, and S3/g-C3N4 composites were synthesized using a simple method. The visible-light photocatalytic degradation efficiency of p-Nitrophenol was enhanced through the synergistic effect of heterojunction and photo-Fenton in the S3/g-C3N4 degradation system, providing a new insight for p-NP removal in the wastewater.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Photocatalytic dyes degradation on suspended and cement paste immobilized TiO2/g-C3N4 under simulated solar light

Shenglei Feng et al.

Summary: TiO2/g-C3N4 powders and TiO2/g-C3N4 cement pastes, fabricated through pyrolysis and spraying methods, exhibit excellent photocatalytic degradation performance, making them promising photocatalysts for large-scale water treatment.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Xin Zhang et al.

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Marzieh Mokarram et al.

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Synthesis of mesoporous magnetic Fe2O3/g-C3N4 monoliths for Rhodamine B removal

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Green synthesis of H-ZSM-5 zeolite-anchored O-doped g-C3N4 for photodegradation of Reactive Red 195 (RR 195) under solar light

Xuan Nui Pham et al.

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Fabrication of Z-scheme photocatalysts g-C3N4/Ag3PO4/chitosan for the photocatalytic degradation of ciprofloxacin

Norah S. Alhokbany et al.

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Muhammad Fahad Ehsan et al.

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Photocatalytic properties of PVDF membranes modified with g-C3N4 in the process of Rhodamines decomposition

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SEPARATION AND PURIFICATION TECHNOLOGY (2020)

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Aziz Habibi-Yangjeh et al.

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Hybrid g-C3N4 nanosheet/carbon paper membranes for the photocatalytic degradation of methylene blue

Tianwei Dou et al.

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The advanced photocatalytic degradation of atrazine by direct Z-scheme Cu doped ZnO/g-C3N4

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Study of structural and magnetic properties of cobalt ferrite (CoFe2O4) nanostructures

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Abhishek Sraw et al.

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Magnetic properties of Co3O4 nanoparticles on graphene substrate

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APPLIED SURFACE SCIENCE (2017)

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Carbon vacancy regulated photoreduction of NO to N2 over ultrathin g-C3N4 nanosheets

Guohui Dong et al.

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A comparison study of alkali metal-doped g-C3N4 for visible-light photocatalytic hydrogen evolution

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