Chemically modified sugarcane bagasse-based biocomposites for efficient removal of acid red 1 dye: Kinetics, isotherms, thermodynamics, and desorption studies

Novel eco-friendly and economically favourable chemically modified biosorbents and biosomposites from sugarcane bagasse (SB) has been investigated for the first time for efficient removal of Acid red 1 dye from wastewater. As fabricated biosorbents and biocomposites were characterized analytically. Batch adsorption experiments has been performed to optimize operating parameters and the determined optimum conditions are; pH: 2, dose: 0.05 g, contact time: between 60 and 75 min, initial dye concentration: 400 mg L-1, and temperature: 30 degrees C, at which maximum Acid red 1 dye removal capacities were found (within range of 143.4-205.1 mg g- 1) by as-designed SB-derived chemically modified biosorbents and biocomposites. This high adsorption capacity was accompanied due to its large specific surface area (30.19 m2 g-1) and excessive functional active binding sites. In terms of the nature of adsorption process, kinetic and isothermal studies demonstrated that experimental data shows greater fitness with pseudo 2nd order and Langmuir model. Thermodynamics analysis revealed that the adsorption process is spontaneous, feasible, and exothermic in nature. Adsorption selective studies signifies that lower concentration of co-existing metallic ions were not interfered during the removal of Acid red 1 dye, which confirms that under optimized adsorption conditions the biosorbents and biocomposites exhibited greater affinity for dye molecules. The excessive quantity (82%) of loaded dye molecules within the adsorbents were extracted within the NaOH eluting media which predicts that as designed biocomposites could have capability of reusability. Hence, it is anticipated that this type of novel SB-derived biocomposites could be considered as greener potential candidate material for commercial scale dye removal applications from industrial wastewater.

Automated summary

This study investigated novel eco-friendly and economically favorable chemically modified biosorbents and biosomposites from sugarcane bagasse for efficient removal of Acid red 1 dye from wastewater. The fabricated materials exhibited high adsorption capacity due to their large specific surface area and excessive functional active binding sites. Kinetic and isothermal studies showed that the experimental data fitted well with pseudo 2nd order and Langmuir model. Thermodynamics analysis revealed that the adsorption process was spontaneous, feasible, and exothermic. Selective adsorption studies indicated that the materials exhibited greater affinity for dye molecules and were not affected by co-existing metallic ions. The loaded dye molecules could be extracted for reusability, making the materials a potential candidate for commercial scale dye removal applications from industrial wastewater.