☆ 4.6 Article

Stereodivergent Desymmetrization of Simple Dicarboxylates via Branch-Selective Pd/Cu Catalyzed Allylic Substitution

CHEMISTRY-A EUROPEAN JOURNAL (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Multidisciplinary

Stereodivergent Pd/Cu Catalysis for Asymmetric Desymmetric Alkylation of Allylic Geminal Dicarboxylates

Xiaohong Huo et al.

Summary: A stereodivergent Pd/Cu catalyst system has been developed for the asymmetric desymmetric alkylation of allylic geminal dicarboxylates, enabling the synthesis of beta-hydroxycarbonyl motifs with versatile carbon-carbon double bonds in an enantio- and diastereodivergent manner. The catalytic system shows compatibility with a wide range of substrates and delivers high yields of substituted products with excellent diastereo- and enantioselectivities. The mechanism of this dual Pd/Cu catalytic system has been thoroughly investigated using theoretical calculations.

CCS CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dispersion and Steric Effects on Enantio-/Diastereoselectivities in Synergistic Dual Transition-Metal Catalysis

Bo Li et al.

Summary: Comprehensive computational studies were conducted to investigate the mechanisms of enantioselective Cu/Pd and stereodivergent Cu/Ir dual-catalytic syntheses of alpha,alpha-disubstituted alpha-amino acids (alpha-AAs). The results demonstrate how ligand-encoded chiral information is transferred to the alpha-/beta-sites of the resulting alpha-AAs and how the mode of regio-/stereoselection is altered by differences in transition-metal-stabilized coupling partners.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Diastereodivergent Synthesis of β-Amino Alcohols by Dual-Metal-Catalyzed Coupling of Alkoxyallenes with Aldimine Esters

Minghui Zhu et al.

Summary: The study presents a dual-metal catalyzed diastereodivergent coupling method for the synthesis of beta-amino alcohols with multiple stereoisomers, enabling the concise preparation of natural products such as mycestericins F and G.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent Carbon-Carbon Bond Formation between Iminium and Enolate Intermediates by Synergistic Organocatalysis

Byungjun Kim et al.

Summary: A stereodivergent method for the Michael addition of aryl acetic acid esters to alpha,beta-unsaturated aldehydes has been developed using a combination of a chiral pyrrolidine and a chiral Lewis base as catalysts. The reaction allows for the synthesis of products with high enantio- and diastereoselectivity, which can be further transformed into a variety of valuable enantioenriched structures.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Organic

Enantioselective Radical SN2-Type Alkylation of Morita-Baylis-Hillman Adducts Using Dual Photoredox/Palladium Catalysis

Xiangbin Bai et al.

Summary: This study presents an enantioselective radical alkylation of 4-alkyl-1,4-dihydropyridines with Morita-Baylis-Hillman (MBH) adducts using dual photoredox/palladium catalysis, yielding products with good yields and enantioselectivity. The use of Ding's spiroketal-based bis-(phosphine) (SKP) ligand is crucial for achieving satisfactory regio- and enantioselectivity in this reaction. The resulting alpha,beta-unsaturated ester can be easily reduced to a synthetically useful chiral allyl alcohol.

ORGANIC LETTERS (2021)

添加到收藏夹

Article Chemistry, Physical

Cooperative N-heterocyclic Carbene and Iridium Catalysis Enables Stereoselective and Regiodivergent [3+2] and [3+3] Annulation Reactions

Jian Zhang et al.

Summary: A cooperative NHC/iridium catalysis has been developed for stereo-selective and regiodivergent annulation reactions of 2-indolyl allyl carbonates with enals, yielding biologically important products with high selectivity. By permutations of the enantiomers of the two chiral catalysts, all four stereoisomers of the products with vicinal stereocenters can be obtained.

ACS CATALYSIS (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution: From Design to Applications

Oscar Pamies et al.

Summary: This review covers the evolution, mechanistic understanding, and recent advances in enantioselective Pd-catalyzed allylic substitution, decarboxylative, and oxidative allylic substitutions. The catalytic data and examples of their application are collected, along with discussions on key mechanistic aspects for high selectivity and comparison with other metals. Different nucleophiles employed and ligand types for improved results in asymmetric allylic substitutions are highlighted.

CHEMICAL REVIEWS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synergistic Ir/Cu Catalysis for Asymmetric Allylic Alkylation of Oxindoles: Enantio- and Diastereoselective Construction of Quaternary and Tertiary Stereocenters

Tianhong Wang et al.

Summary: The highly regio-, enantio-, and diastereoselective allylic alkylation of 3-alkyl oxindoles through synergistic iridium and copper catalysis provides a series of 3,3-disubstituted oxindole derivatives containing adjacent quaternary and tertiary stereogenic centers in excellent yields, enantiomeric excess, and diastereomeric ratio. The method demonstrates exclusive branched selectivity, excellent enantio- and diastereoselectivities, and good functional compatibility, with the chiral copper catalyst being crucial for achieving high reactivities and diastereoselectivities under mild reaction conditions.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

添加到收藏夹

Article Chemistry, Physical

Challenges and Opportunities in Multicatalysis

Sebastian Martinez et al.

Summary: Multicatalysis is an emerging field in synthetic chemistry that aims to efficiently convert simple starting materials into complex products, enhancing resource utilization. By utilizing multiple catalysts in single or sequential reactions, multicatalysis enables efficient transformations that reduce time, waste, and cost.

ACS CATALYSIS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantio- and Diastereodivergent Synthesis of Spirocycles through Dual-Metal-Catalyzed [3+2] Annulation of 2-Vinyloxiranes with Nucleophilic Dipoles

Youbin Peng et al.

Summary: This study presents an enantio- and diastereodivergent synthesis of rigid spirocycles through dual-metal catalysis, offering a promising approach for the development of new N-olefin ligands. Preliminary mechanistic studies were conducted to understand the bimetallic catalysis process.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantio- and Diastereodivergent Construction of 1,3-Nonadjacent Stereocenters Bearing Axial and Central Chirality through Synergistic Pd/Cu Catalysis

Jiacheng Zhang et al.

Summary: This study presents a method for the construction of 1,3-nonadjacent stereocenters through Pd/Cu-catalyzed asymmetric synthesis, providing highly enantio- and diastereoselective chiral products; The protocol is applicable to a wide range of substrates, including challenging allenylic esters with less sterically bulky substituents; Moreover, various transformations involving axial-to-central chirality transfer were conducted, yielding useful structural motifs containing nonadjacent stereocenters in a diastereodivergent manner.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Physical

Mechanistic Origins of Stereodivergence in Asymmetric Cascade Allylation and Cyclization Reactions Enabled by Synergistic Cu/Ir Catalysis

Hui Xu et al.

Summary: The stereodivergent synthesis of bioactive tetrahydro-gamma-carbolines was achieved through synergistic chiral Cu/Ir catalysis, involving the generation of three stereogenic centers via two consecutive C-C formation procedures. Density functional theory calculations were used to elucidate the mechanism and stereochemistry origins of the catalytic asymmetric cascade allylation and iso-Pictet-Spengler cyclization reaction. The study provides insights into the control of absolute stereoselectivity by two distinct chiral metal catalysts, offering potential for further development of stereodivergent synthesis via cooperative bimetallic catalysis.

ACS CATALYSIS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Asymmetric hydrogenation for the synthesis of 2-substituted chiral morpholines

Mingxu Li et al.

Summary: Asymmetric hydrogenation of unsaturated morpholines has been achieved using a bisphosphine-rhodium catalyst with a large bite angle, resulting in quantitative yields and excellent enantioselectivities (up to 99% ee) of various 2-substituted chiral morpholines. The hydrogenated products can be converted into key intermediates for bioactive compounds.

CHEMICAL SCIENCE (2021)

添加到收藏夹

Review Chemistry, Organic

Stereodivergent Pd/Cu Catalysis for the Construction of Allenyl Axial Chirality and Central Chirality

Xiaohong Huo et al.

CHINESE JOURNAL OF ORGANIC CHEMISTRY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synergistic Cu/Pd-catalyzed asymmetric allylation: a facile access to α-quaternary cysteine derivatives

Hui-Min Wu et al.

Summary: An efficient synthetic methodology was developed to access biologically important and synthetically useful alpha-quaternary cysteine derivatives via asymmetric catalytic alpha-allylation. A wide array of alpha-quaternary cysteine derivatives were obtained with good to excellent enantioselectivities, and gram-scale asymmetric allylation was performed to maintain high yields. Additionally, synthetic transformations to access chiral spirocyclic compounds proceeded smoothly, demonstrating the utility of this methodology.

CHEMICAL COMMUNICATIONS (2021)

添加到收藏夹

Article Chemistry, Organic

Stereodivergent Pd/Cu catalysis: asymmetric alkylation of racemic symmetrical 1,3-diphenyl allyl acetates

Ling Zhao et al.

Summary: The stereodivergent Pd/Cu catalyst system enables the asymmetric allylic alkylation of symmetrical 1,3-disubstituted allyl acetates with prochiral imino esters, resulting in efficient access to enantiopure products with vicinal stereocenters. The protocol proceeds smoothly under mild reaction conditions, delivering substituted products with high yields and excellent diastereoselectivities (up to >20 : 1 dr) and enantioselectivities (up to >99% ee).

ORGANIC & BIOMOLECULAR CHEMISTRY (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Synergistic Pd/Cu Catalysis in Organic Synthesis

Yue Wu et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Asymmetric Hydrogenation of 2-Amidoacrylates

Yawen Hu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Physical

Asymmetric Hydrogenation of α-Boryl Enamides Enabled by Nonbonding Interactions

Dongyang Fan et al.

ACS CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Physical

Diastereodivergent synthesis of enantioenriched alpha,beta-disubstituted gamma-butyrolactones via cooperative N-heterocyclic carbene and Ir catalysis

Santanu Singha et al.

NATURE CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent Pd/Cu Catalysis for the Dynamic Kinetic Asymmetric Transformation of Racemic Unsymmetrical 1,3-Disubstituted Allyl Acetates

Rui He et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Editorial Material Multidisciplinary Sciences

Stereodivergent catalytic asymmetric allylic alkylation (AAA)

Subarna Jyoti Kalita et al.

SCIENCE BULLETIN (2020)

添加到收藏夹

Article Chemistry, Organic

Stereodivergent Synthesis of α-Quaternary Serine and Cysteine Derivatives Containing Two Contiguous Stereogenic Centers via Synergistic Cu/Ir Catalysis

Hui-Min Wu et al.

ORGANIC LETTERS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Synergistic Dual Transition Metal Catalysis

U. Bin Kim et al.

CHEMICAL REVIEWS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Asymmetric Hydrogenation of N-Sulfonyl Imines

Bowen Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Regio- and Stereodivergent Synthesis of Homoallylic Amines by a One-Pot Cooperative-Catalysis-Based Allylic Alkylation/Hofmann Rearrangement Strategy

Colin M. Pearson et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Iridium-Catalyzed Asymmetric Synthesis of Functionally Rich Molecules Enabled by (Phosphoramidite,Olefin) Ligands

Simon L. Rossler et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Chemo- and Enantioselective Hydrogenation of α-Formyl Enamides: An Efficient Access to Chiral α-Amido Aldehydes

Jian Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts

Zhi-Tao He et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent Coupling of 1,3-Dienes with Aldimine Esters Enabled by Synergistic Pd and Cu Catalysis

Qinglong Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Mechanistic Analysis of the Palladium-Catalyzed Formation of Branched Allylic Amines Reveals the Origin of the Regio- and Enantioselectivity through a Unique Inner-Sphere Pathway

Lingfei Hu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Cobalt-Catalyzed Asymmetric Hydrogenation of C=N Bonds Enabled by Assisted Coordination and Nonbonding Interactions

Yanhua Hu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Physical

Orbital-Weighted Dual Descriptor for the Study of Local Reactivity of Systems with (Quasi-) Degenerate States

Ricardo Pino-Rios et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2019)

添加到收藏夹

Article Chemistry, Applied

Enantioselective and Diastereodivergent Access to α-Substituted α-Amino Acids via Dual Iridium and Copper Catalysis

Jiacheng Zhang et al.

ADVANCED SYNTHESIS & CATALYSIS (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

Qiang Cheng et al.

CHEMICAL REVIEWS (2019)

添加到收藏夹

Article Multidisciplinary Sciences

Stereodivergent assembly of tetrahydro-γ-carbolines via synergistic catalytic asymmetric cascade reaction

Shi-Ming Xu et al.

NATURE COMMUNICATIONS (2019)

添加到收藏夹

Article Chemistry, Organic

A mechanism exploration of stereodivergent coupling of aldehydes and alkynes catalyzed synergistically by rhodium and amine

Hao-Ran Wei et al.

ORGANIC CHEMISTRY FRONTIERS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Pd/Cu dual catalysis: highly enantioselective access to α-substituted α-amino acids and α-amino amides

Xiaohong Huo et al.

CHEMICAL COMMUNICATIONS (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

Stereodivergent Catalysis

Irina P. Beletskaya et al.

CHEMICAL REVIEWS (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

Non-Bonding Interactions Enable the Selective Formation of Branched Products in Palladium-Catalyzed Allylic Substitution Reactions

Ya-Ni Wang et al.

CHEMISTRY-AN ASIAN JOURNAL (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Domino Process toward Functionally Dense Quaternary Carbons through Pd-Catalyzed Decarboxylative C(sp(3))-C(sp(3)) Bond Formation

Wusheng Guo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent Synthesis of α,α-Disubstituted α-Amino Acids via Synergistic Cu/Ir Catalysis

Liang Wei et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Highly Enantioselective [5+2] Annulations through Cooperative N-Heterocyclic Carbene (NHC) Organocatalysis and Palladium Catalysis

Santanu Singha et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis

Xingyu Jiang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ir/Cu Dual Catalysis: Enantio- and Diastereodivergent Access to alpha,alpha-Disubstituted alpha-Amino Acids Bearing Vicinal Stereocenters

Xiaohong Huo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Organic

Intermolecular Stereoselective Iridium-Catalyzed Allylic Alkylation: An Evolutionary Account

Samantha E. Shockley et al.

SYNLETT (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantioselective Allylic Alkylation with 4-Alkyl-1,4-dihydropyridines Enabled by Photoredox/Palladium Cocatalysis

Hong-Hao Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Organic

Stereoselective Allylic Alkylation of 1-Pyrroline-5-carboxylic Esters via a Pd/Cu Dual Catalysis

Penglin Liu et al.

ORGANIC LETTERS (2018)

添加到收藏夹

Article Multidisciplinary Sciences

Pd(OAc)(2)-catalyzed asymmetric hydrogenation of sterically hindered N-tosylimines

Jianzhong Chen et al.

NATURE COMMUNICATIONS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Asymmetric Allylic Allylation of Racemic Morita-Baylis-Hillman Adducts

Xubin Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis

Xingyu Jiang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereoselective and Site-Specific Allylic Alkylation of Amino Acids and Small Peptides via a Pd/Cu Dual Catalysis

Xiaohong Huo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent Coupling of Aldehydes and Alkynes via Synergistic Catalysis Using Rh and Jacobsen's Amine

Faben A. Cruz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nine-Membered Benzofuran-Fused Heterocycles: Enantioselective Synthesis by Pd-Catalysis and Rearrangement via Transannular Bond Formation

Zi-Qiang Rong et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantioselective Construction of Tertiary C-O Bond via Allylic Substitution of Vinylethylene Carbonates with Water and Alcohols

Ajmal Khan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Stereodivergence in Asymmetric Catalysis

Simon Krautwald et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Review Chemistry, Organic

Cooperative bimetallic catalysis in asymmetric allylic substitution

Jingke Fu et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Organic

Pd-Catalyzed Enantio- and Regioselective Formation of Allylic Aryl Ethers

Jianing Xie et al.

ORGANIC LETTERS (2017)

添加到收藏夹

Article Chemistry, Organic

Ir/Zn Dual Catalysis: Enantioselective and Diastereodivergent α-Allylation of Unprotected α-Hydroxy Indanones

Rui He et al.

ORGANIC LETTERS (2017)

添加到收藏夹

Article Chemistry, Organic

Hydrogen Bond Direction Enables Palladium-Catalyzed Branch- and Enantioselective Allylic Aminations and Beyond

Ya-Ni Wang et al.

ORGANIC LETTERS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Bimetallic catalysis for C-C and C-X coupling reactions

Dominic R. Pye et al.

CHEMICAL SCIENCE (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Applications of Iridium-Catalyzed Asymmetric Allylic Substitution Reactions in Target-Oriented Synthesis

Jianping Qu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Asymmetric Synthesis of ,-Disubstituted Allylic Amines through Palladium-Catalyzed Allylic Substitution

Wusheng Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Catalytic Strategies for Diastereodivergent Synthesis

Lili Lin et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Asymmetric Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters by Allylation of β-Ketocarbonyls with Morita-Baylis-Hillman Adducts

Jiawang Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Switchable divergent asymmetric synthesis via organocatalysis

Gu Zhan et al.

CHEMICAL SOCIETY REVIEWS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Construction of Nine-Membered Heterocycles through Palladium-Catalyzed Formal [5+4] Cycloaddition

Li-Cheng Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Review Chemistry, Applied

Advances in Asymmetric Diastereodivergent Catalysis

Manisha Bihani et al.

ADVANCED SYNTHESIS & CATALYSIS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Chemo- and Enantioselective C-O Bond Cleavage of α-Acyloxy Ketones by Hydrogenolysis

Jianzhong Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Regio- and Enantioselective Synthesis of Allylic Amines Featuring Tetrasubstituted Tertiary Carbons

Aijie Cai et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereoselective and Versatile Preparation of Tri- and Tetrasubstituted Allylic Amine Scaffolds under Mild Conditions

Wusheng Guo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

An Ir/Zn Dual Catalysis for Enantio- and Diastereodivergent α-Allylation of α-Hydroxyketones

Xiaohong Huo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Organic

Palladium-Catalyzed Stereoselective Formation of Substituted Allylic Thioethers and Sulfones

Jose Enrique Gomez et al.

ORGANIC LETTERS (2016)

添加到收藏夹

Article Multidisciplinary Sciences

Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism

Da-Chang Bai et al.

NATURE COMMUNICATIONS (2016)

添加到收藏夹

Article Chemistry, Physical

Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates

J. Caleb Hethcox et al.

ACS CATALYSIS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent Dual Catalytic α-Allylation of Protected α-Amino- and α-Hydroxyacetaldehydes

Tobias Sandmeier et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Asymmetric γ-Allylation of α,β-Unsaturated Aldehydes by Combined Organocatalysis and Transition-Metal Catalysis

Line Naesborg et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Review Chemistry, Multidisciplinary

Transition metal-catalyzed allylic substitution reactions with unactivated allylic substrates

Nicholas A. Butt et al.

CHEMICAL SOCIETY REVIEWS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Origin of Stereodivergence in Cooperative Asymmetric Catalysis with Simultaneous Involvement of Two Chiral Catalysts

Bangaru Bhaskararao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Organic

Hydrogen-Bond Directed Regioselective Pd-Catalyzed Asymmetric Allylic Alkylation: The Construction of Chiral α-Amino Acids with Vicinal Tertiary and Quaternary Stereocenters

Xuan Wei et al.

ORGANIC LETTERS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Enantioselective Decarboxylative Cycloaddition of Vinylethylene Carbonates with Isocyanates

Ajmal Khan et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Asymmetric Decarboxylative Cycloaddition of Vinylethylene Carbonates with Michael Acceptors: Construction of Vicinal Quaternary Stereocenters

Ajmal Khan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study

Xiaohong Huo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Decarboxylative Cycloaddition of Vinylethylene Carbonates with Formaldehyde: Enantioselective Construction of Tertiary Vinylglycols

Ajmal Khan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita-Baylis-Hillman Adducts: Exceptionally High Efficiency and New Mechanism

Xiaoming Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Congested C-C Bonds by Pd-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling, a Mechanism-Guided Solution

Michael J. Ardolino et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereodivergent α-Allylation of Linear Aldehydes with Dual Iridium and Amine Catalysis

Simon Krautwald et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Article Chemistry, Organic

Hydrogen-Bond-Activated Palladium-Catalyzed Allylic Alkylation via Allylic Alkyl Ethers: Challenging Leaving Groups

Xiaohong Huo et al.

ORGANIC LETTERS (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Asymmetric Hydrogenation of α-Acyloxy-1-arylethanones

Jianzhong Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Asymmetric Allylic Alkylation of 3-Aryloxindoles with Allylidene Dipivalate: A Useful Enol Pivalate Product

Barry M. Trost et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dual Catalysis Becomes Diastereodivergent

Maria Teresa Oliveira et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Organic

Achieving Control over the Branched/Linear Selectivity in Palladium-Catalyzed Allylic Amination

Igor Dubovyk et al.

JOURNAL OF ORGANIC CHEMISTRY (2013)

添加到收藏夹

Article Chemistry, Organic

The synthesis of chiral β-aryl-α,β-unsaturated amino alcohols via a Pd-catalyzed asymmetric allylic amination

Mao Quan et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2013)

添加到收藏夹

Editorial Material Multidisciplinary Sciences

A New Twist on Cooperative Catalysis

Corinna S. Schindler et al.

SCIENCE (2013)

添加到收藏夹

Article Multidisciplinary Sciences

Enantio- and Di Aereodivergent Dual Catalysis: α-Allylation of Branched Aldehydes

Simon Krautwald et al.

SCIENCE (2013)

添加到收藏夹

Review Chemistry, Organic

Transition-Metal-Catalyzed Allylic Substitution Reactions: Stereoselective Construction of α- and β-Substituted Carbonyl Compounds

Samuel Oliver et al.

SYNTHESIS-STUTTGART (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Aromatic Spiroketal Bisphosphine Ligands: Palladium-Catalyzed Asymmetric Allylic Amination of Racemic Morita-Baylis-Hillman Adducts

Xiaoming Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synergistic catalysis: A powerful synthetic strategy for new reaction development

Anna E. Allen et al.

CHEMICAL SCIENCE (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Chemo- and Regioselectivity-Tunable Pd-Catalyzed Allylic Alkylation of Imines

Jian-Ping Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

C-N Bond Cleavage of Allylic Amines via Hydrogen Bond Activation with Alcohol Solvents in Pd-Catalyzed Allylic Alkylation of Carbonyl Compounds

Xiaohu Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

添加到收藏夹

Review Chemistry, Multidisciplinary

Biaryl Phosphites: New Efficient Adaptative Ligands for Pd-Catalyzed Asymmetric Allylic Substitution Reactions

Montserrat Dieguez et al.

ACCOUNTS OF CHEMICAL RESEARCH (2010)

添加到收藏夹

Review Chemistry, Multidisciplinary

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

John F. Hartwig et al.

ACCOUNTS OF CHEMICAL RESEARCH (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates

Jian-Ping Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Revealing Noncovalent Interactions

Erin R. Johnson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C-X bond formation

Barry M. Trost et al.

CHEMICAL SCIENCE (2010)

添加到收藏夹

Review Chemistry, Multidisciplinary

Metal-catalyzed enantioselective allylation in asymmetric synthesis

Zhan Lu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

Chasing the proton culprit from palladium-catalyzed allylic amination

Igor Dubovyk et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

添加到收藏夹

Review Chemistry, Multidisciplinary

Enantioselective Tsuji allylations

Justin T. Mohr et al.

CHEMISTRY-AN ASIAN JOURNAL (2007)

添加到收藏夹

Review Chemistry, Multidisciplinary

Predicting the stereochemistry of diphenylphosphino benzoic acid (DPPBA)-based palladium-catalyzed asymmetric allylic alkylation reactions: A working model

Barry M. Trost et al.

ACCOUNTS OF CHEMICAL RESEARCH (2006)

添加到收藏夹

Article Chemistry, Multidisciplinary

S,O-acetals as novel chiral aldehyde equivalents

BM Trost et al.

CHEMISTRY-A EUROPEAN JOURNAL (2006)

添加到收藏夹

Review Chemistry, Multidisciplinary

New insights into the mechanism of palladium-catalyzed allylic amination

IDG Watson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

添加到收藏夹

Article Chemistry, Organic

Palladium/BINAP(S)-catalyzed asymmetric allylic amination

JW Faller et al.

ORGANIC LETTERS (2005)

添加到收藏夹

Review Chemistry, Multidisciplinary

Asymmetric catalysis with chiral ferrocene ligands

LX Dai et al.

ACCOUNTS OF CHEMICAL RESEARCH (2003)

添加到收藏夹

Review Chemistry, Multidisciplinary

Asymmetric transition-metal-catalyzed allylic alkylations: Applications in total synthesis

BM Trost et al.

CHEMICAL REVIEWS (2003)

添加到收藏夹

Review Chemistry, Multidisciplinary

Palladium-assisted routes to nucleosides

LA Agrofoglio et al.

CHEMICAL REVIEWS (2003)

添加到收藏夹

Article Chemistry, Multidisciplinary

Highly regio- and enantioselective Pd-catalyzed allylic alkylation and amination of monosubstituted allylic acetates with novel ferrocene P,N-ligands

SL You et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)

添加到收藏夹

Article Chemistry, Multidisciplinary

Geminal dicarboxylates as carbonyl surrogates for asymmetric synthesis. Part I. Asymmetric addition of malonate nucleophiles

BM Trost et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)

添加到收藏夹

Article Chemistry, Multidisciplinary

Geminal dicarboxylates as carbonyl surrogates for asymmetric synthesis. Part II. Scope and applications

BM Trost et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dynamic kinetic asymmetric transformation of diene monoepoxides: A practical asymmetric synthesis of vinylglycinol, vigabatrin, and ethambutol

BM Trost et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)

添加到收藏夹

Review Chemistry, Multidisciplinary

Phosphinooxazolines - A new class of versatile, modular P,N-ligands for asymmetric catalysis

G Helmchen et al.

ACCOUNTS OF CHEMICAL RESEARCH (2000)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.