期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 28, 期 48, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202201209
关键词
halogen bond; heteroditopic rotaxane; hydrogen bond; Ion-pair; lithium halide
资金
- E.P.A Cephalosporin Scholarship fund, Linacre College
- EPSRC Centre for Doctoral Training, Theory and Modelling in Chemical Sciences [EP/L015722/1]
- Linacre College
- Department of Chemistry, University of Oxford
- EPSRC [EP/P033490/1]
This study investigated the ability of a family of novel halogen bonding and hydrogen bonding heteroditopic rotaxane host systems to recognize lithium halide ion-pairs. The results showed that the rotaxane hosts exhibited selectivity for LiBr over LiI, and the strength of halide binding increased with the number of halogen bond donors integrated into the interlocked cavity. DFT calculations confirmed these findings, revealing the mode of LiX ion-pair binding. The cooperative, heteroditopic, rotaxane axle-macrocycle component mechanical bond effect was identified as an efficient strategy for ion-pair recognition in general.
A family of novel halogen bonding (XB) and hydrogen bonding (HB) heteroditopic [2]rotaxane host systems constructed by active metal template (AMT) methodology, were studied for their ability to cooperatively recognise lithium halide (LiX) ion-pairs. H-1 NMR ion-pair titration experiments in CD3CN:CDCl3 solvent mixtures revealed a notable switch-on of halide anion binding in the presence of a co-bound lithium cation, with rotaxane hosts demonstrating selectivity for LiBr over LiI. The strength of halide binding was shown to greatly increase with increasing number of halogen bond donors integrated into the interlocked cavity, where an all-XB rotaxane was found to be the most potent host for LiBr. DFT calculations corroborated these findings, determining the mode of LiX ion-pair binding. Notably, ion-pair binding was not observed with the corresponding XB/HB macrocycles alone, highlighting the cooperative, heteroditopic, rotaxane axle-macrocycle component mechanical bond effect as an efficient strategy for ion-pair recognition in general.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据