期刊
CHEMICAL REVIEWS
卷 122, 期 12, 页码 10581-10598出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.1c00583
关键词
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资金
- Deutsche Forschungsgemeinschaft [Schm344/49-1]
- CONICET, Argentina
- state of Baden-Wurttemberg through bwHPC
- German Research Foundation (DFG) [INST 40/575-1 FUGG]
This review presents various aspects of electron transfer theory, from the early work of Marcus and Hush to recent developments. Emphasis is placed on the electronic properties of the electrode and their relation to experimental works.
Electron transfer is the most important electrochemical process. In this review, we present elements of various aspects of electron transfer theory from the early work of Marcus and Hush to recent developments. The emphasis is on the role of the electronic, and to a lesser extent the geometrical, properties of the electrode. A variety of experimental works are discussed in light of these theoretical concepts. Because the field of electron transfer is so vast, this review is far from comprehensive; rather, we focus on systems that offer a special interest and illuminate aspects of the theory.
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