期刊
CHEMICAL GEOLOGY
卷 599, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.chemgeo.2022.120846
关键词
High mercury enrichment; Reducing conditions; Volcanic activities; Alum Shale; Late Cambrian
资金
- GeoCenter Denmark project 2017-3
- NSF-EAR grant [2051199]
- CSC scholarship
- Spackman award
- [SKLOG202115]
- Division Of Earth Sciences
- Directorate For Geosciences [2051199] Funding Source: National Science Foundation
This study investigates mercury enrichments in a unique Alum Shale drilled core from southeast Sweden during the late Miaolingian to Furongian period. Four mercury anomalies were found, with the most pronounced one attributed to volcanic activities.
The late Cambrian witnessed significant biological and environmental changes. However, the main triggers responsible for that formidable turnover remain largely unknown. This study investigates mercury (Hg) enrichments from the late Miaolingian to Furongian section in a unique Alum Shale drilled core obtained from southeast Sweden. Our results show that the background level of Hg is relatively high because of the presence of reducing conditions and continuous Hg supply from water mass. However, our most spectacular findings are the presence of four Hg anomalies. The most pronounced Hg anomalies are characterized by the high values in total Hg (similar to 900 ppb) and Hg/TOC ratio (similar to 80), as well as specific signatures of mass independent fractionation of Hg (MIF5; Delta Hg-199, Delta Hg-201, and Delta Hg-200) that we attribute to volcanic-derived Hg. This Hg loading event occurred immediately after the globally recognized Steptoean Positive Carbon Isotope Excursion (SPICE) event and could be attributed to volcanic activities during that period.
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