期刊
CHEMICAL ENGINEERING SCIENCE
卷 255, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2022.117676
关键词
Dry reforming; Glycerol; Synthesis; Ni catalyst; Magnesium silicate
资金
- University of Kashan [573921/1]
Ni-based catalysts supported on magnesium silicate were synthesized and investigated for the glycerol-DR process. The synthesis route of Ni/MgO.SiO2 catalyst was found to be effective in determining the structural and physicochemical features of the sample. The catalyst exhibited high catalytic performance and stability during the glycerol-DR reaction.
Ni-based catalysts supported on magnesium silicate were synthesized using various synthesis procedures and were then investigated for the first time in the glycerol-DR (dry reforming) process. In general, synthesis procedures for catalyst supports included co-precipitation and hydrothermal, and nickel as active metal was attached to the support simultaneously with support preparing and impregnation technique. The results of characterizations of Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), hydrogen temperature-programmed reduction (TPR-H-2), temperature-programmed oxidation (TPO), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) element mapping, Fourier transform infrared (FTIR), thermogravimetric analysis (TGA-DTA), and the catalytic glycerol-DR reaction tests illustrated that the preparation route of Ni/MgO.SiO2 catalyst is effective in the structural and physicochemical features of the sample. It was observed that the catalysts with various synthesis methods exhibited different activity and stability during the glycerol-DR reaction. However, the highest glycerol conversion (31- 50%) and the yield of both H-2 and CO were achieved over the Ni/MgO.SiO2 (I) catalyst at all reaction temperature ranges (600-750 C). The high catalytic performance of the Ni/MgO.SiO2 (I) sample in the glycerol-DR reaction was related to its textural properties such as surface area (411 m(2) g(-1)), the crystallite size (8.5 nm), and active species dispersion, which were superior for this catalyst in comparison with other samples. This sample also exhibited better catalytic stability during the reaction. Furthermore, synthesis gas (syngas) was produced for all catalysts with an H-2/CO ratio of less than 1.6. These results clearly show a significant impact of the sample synthesis procedure on the catalyst's final physical and chemical properties. The Ni/MgO.SiO2 catalyst prepared with a one-step method showed high potential as a glycerol-DR catalyst for syngas production. (c) 2022 Elsevier Ltd. All rights reserved.
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