期刊
CHEMICAL ENGINEERING JOURNAL
卷 446, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2022.137157
关键词
Ferrite; Multilayer core-shell structure; Composite; Microwave absorption; Impedance matching
资金
- National Natural Science Foundation of China [51372108]
Spherical Gd-Co ferrite nanoparticles with silica and carbon shells were synthesized in this study. Among them, Gd-Co ferrite@silica@carbon exhibited the best microwave absorption performance, with low reflection loss and wide effective absorption band. This excellent performance is attributed to the interaction between magnetic loss and dielectric loss, as well as the excellent impedance matching.
Developing microwave absorbing materials having a low reflection loss (RL) and wide effective absorption band (EAB) is important. In this study, spherical Gd-Co ferrite nanoparticles were synthesized by using a co-precipitation method. Silica and carbon shells were coated on the surface of Gd-Co ferrite particles by poly-merizing tetraethyl orthosilicate and glucose. Three composites were prepared: Gd-Co ferrite@silica, Gd-Co ferrite@carbon, and Gd-Co ferrite@silica@carbon. The results showed that Gd-Co ferrite@silica@carbon exhibited the best absorbing performance, with its RL reaching the minimum value of -46.85 dB and its EAB was 3.14 GHz (8.74-11.88 GHz) at an absorption layer thickness of 2.5 mm and a frequency of 9.93 GHz. This excellent microwave absorption performance is attributed to two factors: the magnetic loss caused by the natural resonance and eddy current loss of Gd-Co ferrite and the dielectric loss enhanced by the interfacial polarization and dipole polarization caused by the multilayer core-shell structure such that the composite has excellent impedance matching. Thus, Gd-Co ferrite@silica@carbon composites can be used as high-performance micro-wave absorption material.
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