期刊
CHEMICAL ENGINEERING JOURNAL
卷 433, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.133765
关键词
Anion intercalation; Solid -state synthesis; Sodium -ion batteries; High rate capability; Interlayer expanded VS4
资金
- National Natural Science Foundation of China [21471040]
A novel and efficient low-temperature solid-state method is developed to synthesize interlayer engineered VS4 for potential high-performance Na-ion storage. The intercalation of [NCN](2-) anion expands the interlayer of VS4, accelerating the Na-ion diffusion, reducing the band gap, and enhancing the electronic conductivity. The IE-VS4 demonstrates outstanding Na-ion storage performance, including ultrafast rate capability, high capacity, and superior cycle stability.
The quasi-layered VS4 is the stacked linear chain structure in which parallel chains are bonded by Van der Waals forces. Considering its wide interlayer and high sulfur content, VS4 is supposed to be a potential high-performance anode material for Na-ion storage. Herein, a novel and efficient low-temperature solid-state method is developed to synthesize interlayer engineered VS4 (IE-VS4). The intercalation of [NCN](2-) anion expands the interlayer of VS4 to accelerate the Na-ion diffusion. Furthermore, The intercalated anion also reduces the band gap of VS4 and enhances the electronic conductivity. Thanks to these merits, the IE-VS4 enables standout Na-ion storage performance in terms of ultrafast rate capability (500 mAh g(-1) at 20 A g(-1)), high capacity and superior cycle stability (550 mAh g(-1) at 5 A g(-1) after 2500 cycles). The developed large-scale synthesis method and the interlayer engineering strategy can synergistically promote the practical application of VS4 in electrochemical energy storage.
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