☆ 4.5 Article

Effect of additives and electrode roughness on the production of hypochlorite sanitizer by the electrolysis of NaCl solution in a batch recycle reactor

CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION (2022)

Efficient photocatalytic chlorine production on bismuth oxychloride in chloride solution

Haipeng Wang et al.

Summary: A novel light-driven chlorine evolution reaction (CER) using bismuth oxychloride (BiOCl) photocatalyst in synthetic seawater has been reported, providing an economical and convenient route for Cl-2 production. The superior Cl-2 production rate achieved is sufficient for methane functionalization and production of chlorine-based disinfectant, opening up prospects for halogen production based on solar energy.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Physical

General Efficacy of Atomically Dispersed Pt Catalysts for the Chlorine Evolution Reaction: Potential-Dependent Switching of the Kinetics and Mechanism

Taejung Lim et al.

Summary: A new CER catalyst Pt-1/CNT composed of atomically dispersed Pt-N-4 sites on carbon nanotubes has been developed, showing excellent activity and selectivity compared to traditional Ru-based mixed metal oxide catalysts. The catalysts demonstrate different reaction orders in low and high overpotential regimes, with the RDS switching from the Volmer step to the Heyrovsky step. These insights provide new understanding in the field of CER catalysis.

ACS CATALYSIS (2021)

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Article Chemistry, Multidisciplinary